{"title":"配体引入的 [P2W12O44(C6H5PO3)2]10-的合成与表征","authors":"Shumpei Take, T. Minato, M. Sadakane","doi":"10.1093/chemle/upae118","DOIUrl":null,"url":null,"abstract":"\n Lacunary polyoxometalates represent a distinctive category of inorganic multidentate ligands that serve as precursors for building organic-inorganic hybrid materials and multinuclear metal oxo clusters. In this study, we successfully synthesized and characterized the organic-inorganic hybrid, [P2W12O44(C6H5PO3)2]10–. Two phenylphosphonato ligands were introduced at both ends of the vacant site to form the unique organic-inorganic-organic structure.","PeriodicalId":9862,"journal":{"name":"Chemistry Letters","volume":null,"pages":null},"PeriodicalIF":1.4000,"publicationDate":"2024-06-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Synthesis and Characterization of Ligand-introduced [P2W12O44(C6H5PO3)2]10–\",\"authors\":\"Shumpei Take, T. Minato, M. Sadakane\",\"doi\":\"10.1093/chemle/upae118\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"\\n Lacunary polyoxometalates represent a distinctive category of inorganic multidentate ligands that serve as precursors for building organic-inorganic hybrid materials and multinuclear metal oxo clusters. In this study, we successfully synthesized and characterized the organic-inorganic hybrid, [P2W12O44(C6H5PO3)2]10–. Two phenylphosphonato ligands were introduced at both ends of the vacant site to form the unique organic-inorganic-organic structure.\",\"PeriodicalId\":9862,\"journal\":{\"name\":\"Chemistry Letters\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":1.4000,\"publicationDate\":\"2024-06-12\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Chemistry Letters\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://doi.org/10.1093/chemle/upae118\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemistry Letters","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1093/chemle/upae118","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Synthesis and Characterization of Ligand-introduced [P2W12O44(C6H5PO3)2]10–
Lacunary polyoxometalates represent a distinctive category of inorganic multidentate ligands that serve as precursors for building organic-inorganic hybrid materials and multinuclear metal oxo clusters. In this study, we successfully synthesized and characterized the organic-inorganic hybrid, [P2W12O44(C6H5PO3)2]10–. Two phenylphosphonato ligands were introduced at both ends of the vacant site to form the unique organic-inorganic-organic structure.
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