抗氧化剂对喷射研磨效率和 Sm2Co17 永磁体粉末特性的影响

Dashuai Xu, Lei Liu, Jianhui Yuan, Bo Zhou, Chuang-Hui Dong, Fengxi Wang, Yong Ding, Ying-Li Sun, A. Yan
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摘要

本研究调查了抗氧化剂对 2:17 型钐钴永磁材料的研磨效率、磁粉特性、微观结构和磁性能的影响。结果表明,添加抗氧化剂有助于改善磁粉之间的分散性,从而使喷射研磨时间缩短 33.3%,磁粉产量提高 15.8%。此外,添加抗氧化剂还能增强磁粉的抗氧化性。在 25 ℃ 的恒温空气环境中存放 48 小时后,磁粉中的 O 含量比未添加抗氧化剂的样品减少了 33%。而在磁体中,O 的含量从 0.21 wt.% 降至 0.14 wt.%,这有助于提高磁体中的有效 Sm 含量和域壁钉扎均匀性。添加了抗氧化剂的磁体具有优异的磁性能:B r = 11.6 kGs、SF = 79.6 %、H cj = 16.8 kOe 和 (BH) max = 32.5 MGOe。
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Effect of antioxidant on the efficiency of jet milling and the powder characteristics of Sm2Co17 permanent magnets
This study investigated the effect of antioxidants on the grinding efficiency, magnetic powder characteristics, microstructure, and magnetic properties of 2:17 type SmCo permanent magnet materials. The results show that adding antioxidants helps improve the dispersion among magnetic powders, leading to a 33.3 % decrease in jet milling time and a 15.8 % increase in magnet powder production yield. Additionally, adding antioxidants enhances the oxidation resistance of the magnetic powders. After being stored in a constant temperature air environment at 25 ℃ for 48 h, the O content in the powder decreased by 33 % compared to samples without antioxidants. While in the magnet body, the O content decreased from 0.21 wt.% to 0.14 wt.%, which helps increase the effective Sm content and domain wall pinning uniformity in the magnet. Excellent magnetic properties were obtained in the magnet with added antioxidants: B r = 11.6 kGs, SF = 79.6 %, H cj = 16.8 kOe, and (BH) max = 32.5 MGOe.
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