聚合物体系中具有多功能作用的含磷氮改性剂研究

IF 0.58 Q4 Materials Science Polymer Science, Series D Pub Date : 2024-06-14 DOI:10.1134/S1995421224700448
N. A. Keibal, V. F. Kablov, V. G. Kochetkov, O. M. Novopol’tseva, K. S. Kazaryan, V. I. Stryukova
{"title":"聚合物体系中具有多功能作用的含磷氮改性剂研究","authors":"N. A. Keibal,&nbsp;V. F. Kablov,&nbsp;V. G. Kochetkov,&nbsp;O. M. Novopol’tseva,&nbsp;K. S. Kazaryan,&nbsp;V. I. Stryukova","doi":"10.1134/S1995421224700448","DOIUrl":null,"url":null,"abstract":"<p>The paper is devoted to the development of a new phosphorus–nitrogen-containing fire retardant with multifunctional action, which is a product of the interaction of dimethylphosphite and dicyandiamide (DDP). The resulting product has a close-to-optimal ratio of nitrogen and phosphorus atoms, which determines its adhesive, thermal stabilizing, and antipyretic activity. DDP has a positive effect on the fire- and heat-protective properties of the material: the time for heating the unheated surface of the sample to 100°C increases by 39–57%, and the linear burning rate decreases by 17–21%. It has been shown that the strength of the adhesive joint increases by an average of 30–70% and the composition containing DDP exhibits consistently better adhesive strength than the original adhesive composition up to 80°C.</p>","PeriodicalId":741,"journal":{"name":"Polymer Science, Series D","volume":"17 2","pages":"266 - 272"},"PeriodicalIF":0.5800,"publicationDate":"2024-06-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"A Study of Phosphorus–Nitrogen-Containing Modifier with Polyfunctional Action in Polymer Systems\",\"authors\":\"N. A. Keibal,&nbsp;V. F. Kablov,&nbsp;V. G. Kochetkov,&nbsp;O. M. Novopol’tseva,&nbsp;K. S. Kazaryan,&nbsp;V. I. Stryukova\",\"doi\":\"10.1134/S1995421224700448\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>The paper is devoted to the development of a new phosphorus–nitrogen-containing fire retardant with multifunctional action, which is a product of the interaction of dimethylphosphite and dicyandiamide (DDP). The resulting product has a close-to-optimal ratio of nitrogen and phosphorus atoms, which determines its adhesive, thermal stabilizing, and antipyretic activity. DDP has a positive effect on the fire- and heat-protective properties of the material: the time for heating the unheated surface of the sample to 100°C increases by 39–57%, and the linear burning rate decreases by 17–21%. It has been shown that the strength of the adhesive joint increases by an average of 30–70% and the composition containing DDP exhibits consistently better adhesive strength than the original adhesive composition up to 80°C.</p>\",\"PeriodicalId\":741,\"journal\":{\"name\":\"Polymer Science, Series D\",\"volume\":\"17 2\",\"pages\":\"266 - 272\"},\"PeriodicalIF\":0.5800,\"publicationDate\":\"2024-06-14\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Polymer Science, Series D\",\"FirstCategoryId\":\"1\",\"ListUrlMain\":\"https://link.springer.com/article/10.1134/S1995421224700448\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"Materials Science\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Polymer Science, Series D","FirstCategoryId":"1","ListUrlMain":"https://link.springer.com/article/10.1134/S1995421224700448","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"Materials Science","Score":null,"Total":0}
引用次数: 0

摘要

本文致力于开发一种具有多功能作用的新型含磷氮阻燃剂,它是亚磷酸二甲酯和双氰胺(DDP)相互作用的产物。由此产生的产品具有接近最佳比例的氮原子和磷原子,这决定了它具有粘合性、热稳定性和解热活性。DDP 对材料的防火和防热性能有积极影响:样品未加热表面加热到 100°C 的时间增加了 39-57%,线性燃烧率降低了 17-21%。研究表明,粘合接头的强度平均提高了 30-70%,含有 DDP 的组合物在高达 80°C 的温度下显示出的粘合强度始终优于原始粘合组合物。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

摘要图片

摘要图片

查看原文
分享 分享
微信好友 朋友圈 QQ好友 复制链接
本刊更多论文
A Study of Phosphorus–Nitrogen-Containing Modifier with Polyfunctional Action in Polymer Systems

The paper is devoted to the development of a new phosphorus–nitrogen-containing fire retardant with multifunctional action, which is a product of the interaction of dimethylphosphite and dicyandiamide (DDP). The resulting product has a close-to-optimal ratio of nitrogen and phosphorus atoms, which determines its adhesive, thermal stabilizing, and antipyretic activity. DDP has a positive effect on the fire- and heat-protective properties of the material: the time for heating the unheated surface of the sample to 100°C increases by 39–57%, and the linear burning rate decreases by 17–21%. It has been shown that the strength of the adhesive joint increases by an average of 30–70% and the composition containing DDP exhibits consistently better adhesive strength than the original adhesive composition up to 80°C.

求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
Polymer Science, Series D
Polymer Science, Series D Materials Science-Polymers and Plastics
CiteScore
0.80
自引率
0.00%
发文量
87
期刊介绍: Polymer Science, Series D  publishes useful description of engineering developments that are related to the preparation and application of glues, compounds, sealing materials, and binding agents, articles on the adhesion theory, prediction of the strength of adhesive joints, methods for the control of their properties, synthesis, and methods of structural modeling of glued joints and constructions, original articles with new scientific results, analytical reviews of the modern state in the field.
期刊最新文献
Studying the Properties of Paint-and-Varnish Materials Application of Ultrasonic Vibrations in the Course of Gluing The Influence of Hydrocarbon Resins on the Properties of Polyisobutylene-Based Hot-Melt Adhesives Welding of Parts Made of Polymer Composite Materials Based on Thermoplastics. Part 3. Methods for Welding Parts Made of Polymer Composite Materials Based on Thermoplastics with the Conversion of Various Types of Energy Studies on the Climatic Resistance of Thiokol and Siloxane Sealant
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
已复制链接
已复制链接
快去分享给好友吧!
我知道了
×
扫码分享
扫码分享
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1