Sara Reyhanian, Ali Elhampour, Majid M. Heravi, Firouzeh Nemati
{"title":"制备用于 Mizoroki-Heck 交叉偶联反应的、封装在介孔聚美尔胺甲醛 Yolk-Shell 纳米反应器中的高活性和稳定的磁性可分离 Pd NPs","authors":"Sara Reyhanian, Ali Elhampour, Majid M. Heravi, Firouzeh Nemati","doi":"10.1007/s11164-024-05331-4","DOIUrl":null,"url":null,"abstract":"<p>The Yolk-Shell nanoreactors, characterized by a void region separating the core from the shell, are recognized as superior heterogeneous catalysts because of their enhanced mass transport capacity, robust stability, and remarkable catalytic performance. A hollow Yolk-Shell nanoreactor involving, CuFe<sub>2</sub>O<sub>4</sub> magentic nanoparticles (MNPs) as the Yolk and mesoporous polymelamine formaldehyde (m-PMF) was prepared as the shell, together with palladium nanoparticles (NPs) stabilized on the surface of CuFe<sub>2</sub>O<sub>4</sub> MNPs and encapsulated in the void space. Its structure was fully characterized using different analyses, obtained from Fourier transform infrared (FT-IR), scanning electron microscopy (SEM), energy-dispersive X-ray (EDX), X‐ray diffraction (XRD), N<sub>2</sub> Adsorption–Desorption, transmission electron microscopies (TEM), and vibrating sample magnetometry (VSM) techniques. The permeable and durable m-PMF shell that encased the Pd NPs facilitated the reaction within the empty cavity. Following this, the Yolk-Shell CuFe<sub>2</sub>O<sub>4</sub>@Pd@HM-PMF nanoreactor, known for its hollow structure, was evaluated as a proficient catalyst in the Mizoroki–Heck coupling reaction. Additionally, it demonstrated magnetic separability and exhibited satisfactory recyclability.</p><h3 data-test=\"abstract-sub-heading\">Graphical Abstract</h3>","PeriodicalId":753,"journal":{"name":"Research on Chemical Intermediates","volume":null,"pages":null},"PeriodicalIF":2.8000,"publicationDate":"2024-07-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Preparation of highly active and stable magnetically separable Pd NPs encapsulated in mesoporous polymelamine formaldehyde Yolk-Shell nanoreactor for the Mizoroki–Heck cross-coupling reaction\",\"authors\":\"Sara Reyhanian, Ali Elhampour, Majid M. Heravi, Firouzeh Nemati\",\"doi\":\"10.1007/s11164-024-05331-4\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>The Yolk-Shell nanoreactors, characterized by a void region separating the core from the shell, are recognized as superior heterogeneous catalysts because of their enhanced mass transport capacity, robust stability, and remarkable catalytic performance. A hollow Yolk-Shell nanoreactor involving, CuFe<sub>2</sub>O<sub>4</sub> magentic nanoparticles (MNPs) as the Yolk and mesoporous polymelamine formaldehyde (m-PMF) was prepared as the shell, together with palladium nanoparticles (NPs) stabilized on the surface of CuFe<sub>2</sub>O<sub>4</sub> MNPs and encapsulated in the void space. Its structure was fully characterized using different analyses, obtained from Fourier transform infrared (FT-IR), scanning electron microscopy (SEM), energy-dispersive X-ray (EDX), X‐ray diffraction (XRD), N<sub>2</sub> Adsorption–Desorption, transmission electron microscopies (TEM), and vibrating sample magnetometry (VSM) techniques. The permeable and durable m-PMF shell that encased the Pd NPs facilitated the reaction within the empty cavity. Following this, the Yolk-Shell CuFe<sub>2</sub>O<sub>4</sub>@Pd@HM-PMF nanoreactor, known for its hollow structure, was evaluated as a proficient catalyst in the Mizoroki–Heck coupling reaction. Additionally, it demonstrated magnetic separability and exhibited satisfactory recyclability.</p><h3 data-test=\\\"abstract-sub-heading\\\">Graphical Abstract</h3>\",\"PeriodicalId\":753,\"journal\":{\"name\":\"Research on Chemical Intermediates\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":2.8000,\"publicationDate\":\"2024-07-02\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Research on Chemical Intermediates\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://doi.org/10.1007/s11164-024-05331-4\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Research on Chemical Intermediates","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1007/s11164-024-05331-4","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Preparation of highly active and stable magnetically separable Pd NPs encapsulated in mesoporous polymelamine formaldehyde Yolk-Shell nanoreactor for the Mizoroki–Heck cross-coupling reaction
The Yolk-Shell nanoreactors, characterized by a void region separating the core from the shell, are recognized as superior heterogeneous catalysts because of their enhanced mass transport capacity, robust stability, and remarkable catalytic performance. A hollow Yolk-Shell nanoreactor involving, CuFe2O4 magentic nanoparticles (MNPs) as the Yolk and mesoporous polymelamine formaldehyde (m-PMF) was prepared as the shell, together with palladium nanoparticles (NPs) stabilized on the surface of CuFe2O4 MNPs and encapsulated in the void space. Its structure was fully characterized using different analyses, obtained from Fourier transform infrared (FT-IR), scanning electron microscopy (SEM), energy-dispersive X-ray (EDX), X‐ray diffraction (XRD), N2 Adsorption–Desorption, transmission electron microscopies (TEM), and vibrating sample magnetometry (VSM) techniques. The permeable and durable m-PMF shell that encased the Pd NPs facilitated the reaction within the empty cavity. Following this, the Yolk-Shell CuFe2O4@Pd@HM-PMF nanoreactor, known for its hollow structure, was evaluated as a proficient catalyst in the Mizoroki–Heck coupling reaction. Additionally, it demonstrated magnetic separability and exhibited satisfactory recyclability.
期刊介绍:
Research on Chemical Intermediates publishes current research articles and concise dynamic reviews on the properties, structures and reactivities of intermediate species in all the various domains of chemistry.
The journal also contains articles in related disciplines such as spectroscopy, molecular biology and biochemistry, atmospheric and environmental sciences, catalysis, photochemistry and photophysics. In addition, special issues dedicated to specific topics in the field are regularly published.