聚酯树脂复合材料上氧化锡纳米和微结构的伽马射线屏蔽研究:实验和理论研究

IF 3.2 3区 化学 Q2 POLYMER SCIENCE e-Polymers Pub Date : 2024-06-29 DOI:10.1515/epoly-2024-0039
Wafa M. Al-Saleh, Haifa M. Almutairi, Khalid Alsafi, Islam M. Nabil, Mohamed Elsafi
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引用次数: 0

摘要

基于实验和理论辐射衰减,本研究制作并测试了一种由不同浓度氧化锡增强的聚酯制成的复合材料,简称为 Pol-SnOx,其中 x = 0-60%,步长为 20 wt%:微粒、纳米和 50% 微粒/50% 纳米混合物,以研究粒度对辐射衰减性能的影响。在 0.015-15 MeV 的光子能量范围内,使用 HPGe 探测器对它们的辐射屏蔽性能进行了经验测定,并使用 Phy-X/PSD 软件对它们的辐射屏蔽性能进行了理论测定。在 0.015 至 15 MeV 的光子能量(Eγ)范围内,Pol-SnO0 的线性衰减系数(LAC)值从 1.361 降至 0.022 cm-1,Pol-SnO20 从 13.611 降至 0.033 cm-1,Pol-SnO40 从 31.700 降至 0.049 cm-1,Pol-SnO60 从 61.076 降至 0.076 cm-1。随着氧化锡浓度的增加,制备的 Pol-SnOx 样品的 LAC 值也在增加。此外,在聚酯中添加 50% 微米/50% 纳米混合粒径的氧化锡也显著提高了 LAC 值。在 Eγ 值为 0.059、0.661、1.173 和 1.332 MeV 时,SnO 纳米粒子的 LAC 改善百分比分别为 16.625%、13.236%、8.714% 和 7.935%。此外,在 Eγ 值为 0.059、0.661、1.173 和 1.332 MeV 时,与微颗粒相比,添加含 50%微米/50%纳米混合颗粒的氧化锡可使 LAC 值分别提高 19.097%、15.271%、9.854% 和 9.071%。在聚酯中添加 50% 微米/50% 纳米混合氧化锡(含量为 60%)后,在其他样品中显示出最高的 LAC 和辐射防护效率,以及最低的半值层和透射系数,这是因为微米和纳米混合体中氧化锡的掺杂量和粒子间距离增加了。
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Gamma-ray shielding investigation of nano- and microstructures of SnO on polyester resin composites: Experimental and theoretical study
Based on the experimental and theoretical radiation attenuation, this study produced and tested a composite material made of polyester reinforced with SnO at varied concentrations and abbreviated as Pol-SnOx, where x = 0–60% with steps of 20 wt% Also, the polyester samples were doped with SnO of different particle sizes: Micro, Nano, and 50% Micro/50% Nano mix to investigate the effect of the particle size on the radiation attenuation performance. In the photon energy range of 0.015–15 MeV, their radiation shielding properties were empirically determined using an HPGe detector and theoretically determined using Phy-X/PSD software. The linear attenuation coefficient (LAC) values dropped from 1.361 to 0.022 cm−1 for Pol-SnO0, from 13.611 to 0.033 cm−1 for Pol-SnO20, from 31.700 to 0.049 cm−1 for Pol-SnO40, and from 61.076 to 0.076 cm−1 for Pol-SnO60 in the photon energy (Eγ) range from 0.015 to 15 MeV. The LAC values of the fabricated Pol-SnOx samples increased as the SnO concentrations increased. Also, the addition of 50% Micro/50% Nano mix particle size of the SnO to the polyester significantly increased the values of the LAC. The percentages of LAC improvement of SnO nano-particles were 16.625%, 13.236%, 8.714%, and 7.935% at the Eγ values of 0.059, 0.661, 1.173, and 1.332 MeV, respectively. Also, the LAC values were enhanced by adding SnO containing 50% Micro/50% Nano mix particles by 19.097%, 15.271%, 9.854%, and 9.071% at the Eγ values of 0.059, 0.661, 1.173, and 1.332 MeV, respectively, when compared to microparticles. The addition of 50% Micro/50% Nano Mix of SnO with 60% content to the polyester showed the highest LAC and radiation protection efficiency and lowest half-value layer and transmission factor among the other samples due to increased SnO doping and interparticle distances of the Micro and Nano mix.
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来源期刊
e-Polymers
e-Polymers 化学-高分子科学
CiteScore
5.90
自引率
10.80%
发文量
64
审稿时长
6.4 months
期刊介绍: e-Polymers is a strictly peer-reviewed scientific journal. The aim of e-Polymers is to publish pure and applied polymer-science-related original research articles, reviews, and feature articles. It includes synthetic methodologies, characterization, and processing techniques for polymer materials. Reports on interdisciplinary polymer science and on applications of polymers in all areas are welcome. The present Editors-in-Chief would like to thank the authors, the reviewers, the editorial staff, the advisory board, and the supporting organization that made e-Polymers a successful and sustainable scientific journal of the polymer community. The Editors of e-Polymers feel very much engaged to provide best publishing services at the highest possible level.
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