氯化铯-磷钨酸盐晶格 Cs9(TlCl6)(PW12O40)2-9CsCl 中的六氯齐酞酸晶体结构。

IF 0.5 Q4 CRYSTALLOGRAPHY Acta Crystallographica Section E: Crystallographic Communications Pub Date : 2024-06-01 DOI:10.1107/S2056989024005565

Gauthier Deblonde , Ian Colliard , Y. Ozawa (Editor)

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引用次数: 0

摘要

氯化铯铊磷钨酸盐 Cs9(TlCl6)(PW12O40)2-9CsCl 的晶体形成展示了通过使用多氧金属盐（POMs）捕获八面体配合物并使其结晶的能力。大量的铯氯化物使得 POM [α-PW12O40]3- 能够排列成立方紧密堆积晶格扩展框架，其中产生的空隙能够捕获 [TlCl6]3- 复合物。

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Crystal structure of hexachlorothallate within a caesium chloride–phosphotungstate lattice Cs9(TlCl6)(PW12O40)2·9CsCl

The cystallization and capture of hexachlorothallium within the phosphotunsgate and caesium chloride matrix is described.

Crystal formation of caesium thallium chloride phosphotungstates, Cs₉(TlCl₆)(PW₁₂O₄₀)₂·9CsCl showcases the ability to capture and crystallize octahedral complexes via the use of polyoxometalates (POMs). The large number of caesium chlorides allows for the POM [α-PW₁₂O₄₀]³⁻ to arrange itself in a cubic close-packing lattice extended framework, in which the voids created enable the capture of the [TlCl₆]³⁻ complex.

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来源期刊

Acta Crystallographica Section E: Crystallographic Communications Chemistry-Chemistry (all)

CiteScore

1.90

自引率

0.00%

发文量

351

审稿时长

3 weeks

期刊介绍： Acta Crystallographica Section E: Crystallographic Communications is the IUCr''s open-access structural communications journal. It provides a fast, simple and easily accessible publication mechanism for crystal structure determinations of inorganic, metal-organic and organic compounds. The electronic submission, validation, refereeing and publication facilities of the journal ensure rapid and high-quality publication of fully validated structures. The primary article category is Research Communications; these are peer-reviewed articles describing one or more structure determinations with appropriate discussion of the science.