改进复杂矿石浮选的试剂制度

Z. Kyaw, A.A. Semikin, D.G. Sandakova, A.A. Dekhtyarenko, V.A. Yakimov
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摘要

俄罗斯的黄铁矿铜锌(硫化)矿和多金属矿是一种复杂而反叛的矿物原料。此类矿石的主要加工技术是浮选。目前,对此类矿物原料浮选技术的改进主要从以下几个方面进行。铜锌矿加工实践证明,在闪锌矿和黄铁矿浮选过程中,如果不使用各种改质剂,就不可能获得高质量的锌精矿和黄铁矿精矿。这些试剂是碱钙介质中的铜(II)、锌和铁(II)硫酸盐。因此,在矿物浮选过程中加入一种指定的硫酸盐后,对闪锌矿和黄铁矿在碱-钙介质中的浮选特性进行了研究。在 pH 值为 8、10 和 12 的条件下,用黄原酸丁酯和二硫代磷酸酯浮选闪锌矿和黄铁矿时,研究了铜(II)、锌和铁(II)硫酸盐对其浮选特性的影响。这项工作的目的是研究巯基捕收剂在硫酸铜、锌和铁存在下对浮选俄罗斯一个矿床中粒度等级为 0.074 + 0.044 毫米的闪锌矿和黄铁矿的影响。
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Enhancement of reagent regimes for complex ores flotation
Pyrite copper-zinc (sulfide) and polymetallic ores in Russia are complex and rebellious mineral raw materials. The main processing technology for such ores is flotation. Enhancement of the flotation technology for such mineral raw materials is currently performed in several directions. The practice of copper-zinc ore processing proves that obtaining highquality zinc and pyrite concentrates is impossible without the use of various modifiers in the sphalerite and pyrite flotation process. Such reagents are copper (II), zinc and iron (II) sulfates in the alkali-calcic medium. Therefore, research was carried out to study floatation properties of sphalerite and pyrite in the alkali-calcic medium with addition of one of the indicated sulfates to the mineral flotation process. The effect of each of the sulfates of copper (II), zinc and iron (II) on the flotation properties of sphalerite and pyrite was studied during flotation of the mineral with butyl xanthate and dithiophosphate at pH equal to 8, 10, and 12. The aim of this work was to study the effect of the sulfhydryl collectors in presence of copper sulfates, zinc and iron for flotation of sphalerite and pyrite with the grain-size class of 0.074 + 0.044 mm from one of the Russian deposits.
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