温度对以生物质废料为还原剂的赤铁矿悬浮磁化焙烧的影响:气体演化的视角

IF 3.7 2区 材料科学 Q1 METALLURGY & METALLURGICAL ENGINEERING Journal of Central South University Pub Date : 2024-07-23 DOI:10.1007/s11771-024-5691-7
Yue Cao, Yong-sheng Sun, Yue-xin Han, Peng Gao, Yan-jun Li
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引用次数: 0

摘要

利用生物质废弃物对赤铁矿进行磁化还原,可有效利用废弃物,减少二氧化碳排放,实现碳峰值和碳中和的目标。利用 TG-FTIR、Py-GC/MS 和气体成分分析仪研究了温度对利用生物质废料进行赤铁矿悬浮磁化焙烧产生挥发气体的影响。混合物还原过程分为四个阶段。在混合物 200-450 °C 的温度范围内,气体产物主要是二氧化碳、酸和酮的释放。当温度从 450 ℃ 升至 900 ℃ 时,小分子还原气体的产量和浓度增加。700 °C 时,CO、H2 和 CH4 的体积浓度分别达到 8.91%、8.90% 和 4.91% 的峰值。在悬浮磁化焙烧过程中,700 °时可获得铁品位为 70.86%、回收率为 98.66%、磁转化率为 45.70%的最佳铁精矿。因此,由于使用了合适的还原气体,在 600 至 700 °C 的温度范围内,磁化还原反应非常显著。这项研究详细展示了焙烧温度下的气体演变过程,为研究利用生物废料还原赤铁矿的过程提供了新的视角。
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Effect of temperature on suspension magnetization roasting of hematite using biomass waste as reductant: A perspective of gas evolution

The magnetization reduction of hematite using biomass waste can effectively utilize waste and reduce CO2 emission to achieve the goals of carbon peaking and carbon neutrality. The effects of temperatures on suspension magnetization roasting of hematite using biomass waste for evolved gases have been investigated using TG-FTIR, Py-GC/MS and gas composition analyzer. The mixture reduction process is divided into four stages. In the temperature range of 200–450 °C for mixture, the release of CO2, acids, and ketones is dominated in gases products. The yield and concentration of small molecules reducing gases increase when the temperature increases from 450 to 900 °C. At 700 °C, the volume concentrations of CO, H2 and CH4 peak at 8.91%, 8.90% and 4.91%, respectively. During the suspension magnetization roasting process, an optimal iron concentrate with an iron grade of 70.86%, a recovery of 98.66% and a magnetic conversion of 45.70% is obtained at 700 °. Therefore, the magnetization reduction could react greatly in the temperature range of 600 to 700 °C owing to the suitable reducing gases. This study shows a detail gaseous evolution of roasting temperature and provides a new insight for studying the reduction process of hematite using biomass waste.

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来源期刊
Journal of Central South University
Journal of Central South University METALLURGY & METALLURGICAL ENGINEERING-
CiteScore
6.10
自引率
6.80%
发文量
242
审稿时长
2-4 weeks
期刊介绍: Focuses on the latest research achievements in mining and metallurgy Coverage spans across materials science and engineering, metallurgical science and engineering, mineral processing, geology and mining, chemical engineering, and mechanical, electronic and information engineering
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