评估 Ni-ZnO/g-C3N4 纳米复合材料的光催化降解有机缺陷和抗菌活性

IF 2.7 4区 化学 Q2 CHEMISTRY, INORGANIC & NUCLEAR Journal of Cluster Science Pub Date : 2024-07-28 DOI:10.1007/s10876-024-02663-4
T. Kavitha, Jothimani Kannupaiyan, Ranjith Rajendran, Aswini Rangayasami
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引用次数: 0

摘要

在本研究中,通过水热法成功制备了一种高效、环保和新型的 Ni-ZnO/g-C3N4 (NZG) 光催化复合材料。利用 XRD 分析确定了所制备的 g-C3N4、Ni-ZnO 和 Ni-ZnO/g-C3N4 纳米复合材料的晶体结构和相纯度。g-C3N4 和 Ni-ZnO 的保留峰都出现了微小的变化,这表明成分之间存在相互作用。利用傅立叶变换红外光谱分析 g-C3N4 和 Ni-ZnO 的组合特征,以及新增的 Zn-O 和 C-N 伸展带,确定官能团并验证复合材料的发展。观察到 g-C3N4、Ni-ZnO 和 Ni-ZnO/g-C3N4 纳米复合材料的光学特性和带隙能分别为 360、380 和 470 nm-1(2.74、2.94 和 2.86 eV)。利用 TEM 分析研究了 Ni-ZnO 纳米粒子的形态和元素组成,结果表明 Ni-ZnO 纳米粒子在 g-C3N4 薄片上分布均匀,界面接触性强,元素组成一致。对 RB5 染料的光催化降解效率进行了研究。在紫外光下 120 分钟后,Ni-ZnO/g-C3N4 纳米复合材料对 RB5 的降解率达到 89.7%,优于纯 Ni-ZnO 和 g-C3N4 催化剂。由于稳定性的增强,Ni-ZnO 和 g-C3N4 之间的电子空穴分离和协同光催化机理也得到了改善,因此对废水处理具有极佳的光催化活性。阳性对照氯霉素对金黄色葡萄球菌和粪肠球菌的抑制区分别为 16 nm 和 18 nm,阴性对照没有抑制区,而 Ni-ZnO/g-C3N4 NCs 对粪肠球菌的最大抑制区分别为 21 nm(100 µg/mL)和 100 µg/mL。
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Evaluate the Ni-ZnO/g-C3N4 Nanocomposite for Photocatalytic Degradation of Organic Defect Degradation and Antibacterial Activity

In the present work, an effective, ecofriendly and novel photocatalytic composite of Ni-ZnO/g-C3N4 (NZG) has been successfully prepared via a hydrothermal method. The crystalline structure and phase purity of the produced g-C3N4, Ni-ZnO, and Ni-ZnO/g-C3N4 nanocomposite were ascertained using XRD analysis. Both the g-C3N4, and Ni-ZnO retained peaks showed minor changes that suggested component interaction. Determine the functional groups and validate the composite’s development using FTIR analysis of the combined g-C3N4, and Ni-ZnO characteristics, along with the addition of new Zn-O and C-N stretching bands. The optical properties and bandgap energy were observed for g-C3N4, Ni-ZnO, and Ni-ZnO/g-C3N4 nanocomposite were 360, 380, and 470 nm−1 with 2.74, 2.94 and 2.86 eV. The homogeneous distribution of Ni-ZnO nanoparticles on g-C3N4, sheets, with strong contact at the interface and consistent elemental composition, was shown by using TEM analysis to investigate the morphological and elemental composition. The photocatalytic degradation efficiency was investigated against RB5 dyes. The Ni-ZnO/g-C3N4 nanocomposite showed excellent than pure Ni-ZnO and g-C3N4 catalyst reached 89.7% degradation for RB5 after 120 min under UV light. Due to this enhanced stability, in addition to the improved electron hole separations and synergistic photocatalytic mechanism between Ni-ZnO and g-C3N4 is an excellent photocatalytic activity against waste water management. The positive control chloramphenicol was showed the inhibition zone was against Sterptococcus aureus and Enterococcus faecalis for 16 nm and 18 nm, for negative control there was no zone of inhibition, and the Ni-ZnO/g-C3N4 NCs showed the maximum zone of inhibition was observed in Enterococcus faecalis for 21 nm at and 100 µg/mL respectively.

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来源期刊
Journal of Cluster Science
Journal of Cluster Science 化学-无机化学与核化学
CiteScore
6.70
自引率
0.00%
发文量
166
审稿时长
3 months
期刊介绍: The journal publishes the following types of papers: (a) original and important research; (b) authoritative comprehensive reviews or short overviews of topics of current interest; (c) brief but urgent communications on new significant research; and (d) commentaries intended to foster the exchange of innovative or provocative ideas, and to encourage dialogue, amongst researchers working in different cluster disciplines.
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