N. L. Bazyakina, A. O. Kochina, E. V. Baranov, I. L. Fedushkin
{"title":"镱(ii)与 1,3-双(吡啶-4-基)丙烷连接体的二维配位聚合物","authors":"N. L. Bazyakina, A. O. Kochina, E. V. Baranov, I. L. Fedushkin","doi":"10.1007/s11172-024-4275-x","DOIUrl":null,"url":null,"abstract":"<p>The reaction of the complex [(dpp-bian)<sup>2−</sup>Yb<sup>2+</sup>(THF)<sub>4</sub>] (dpp-bian is 1,2-bis[(2,6-diisopropylphenyl)imino]acenaphthene) with two molar equivalents of 1,3-bis(pyridin-4-yl)propane (bpp) in tetrahydrofuran (THF) afforded the 2D coordination polymer [{(dpp-bian)Yb(bpp)<sub>2</sub>} • 3 THF]<sub><i>n</i></sub> (<b>1</b>). The reaction of [(dpp-bian)<sup>2−</sup>Yb<sup>2+</sup>(DME)<sub>2</sub>] with phenazine (phz) gave the dimeric complex [{(dpp-bian)Yb(DME)}<sub>2</sub>(μ-η<sup>3</sup>:η<sup>3</sup>-phz)] • 2 DME (<b>2</b>), in which two cationic {(dpp-bian)Yb(DME)} units are connected <i>via</i> a bridging phenazine dianion. Compounds <b>1</b> and <b>2</b> were characterized by elemental analysis and IR spectroscopy. Their molecular structures were determined by single-crystal X-ray diffraction analysis. Thermal stability of compound <b>1</b> was studied by thermogravimetric analysis.</p>","PeriodicalId":756,"journal":{"name":"Russian Chemical Bulletin","volume":null,"pages":null},"PeriodicalIF":1.7000,"publicationDate":"2024-07-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Two-dimensional coordination polymer of ytterbium(ii) with a 1,3-bis(pyridin-4-yl)propane linker\",\"authors\":\"N. L. Bazyakina, A. O. Kochina, E. V. Baranov, I. L. Fedushkin\",\"doi\":\"10.1007/s11172-024-4275-x\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>The reaction of the complex [(dpp-bian)<sup>2−</sup>Yb<sup>2+</sup>(THF)<sub>4</sub>] (dpp-bian is 1,2-bis[(2,6-diisopropylphenyl)imino]acenaphthene) with two molar equivalents of 1,3-bis(pyridin-4-yl)propane (bpp) in tetrahydrofuran (THF) afforded the 2D coordination polymer [{(dpp-bian)Yb(bpp)<sub>2</sub>} • 3 THF]<sub><i>n</i></sub> (<b>1</b>). The reaction of [(dpp-bian)<sup>2−</sup>Yb<sup>2+</sup>(DME)<sub>2</sub>] with phenazine (phz) gave the dimeric complex [{(dpp-bian)Yb(DME)}<sub>2</sub>(μ-η<sup>3</sup>:η<sup>3</sup>-phz)] • 2 DME (<b>2</b>), in which two cationic {(dpp-bian)Yb(DME)} units are connected <i>via</i> a bridging phenazine dianion. Compounds <b>1</b> and <b>2</b> were characterized by elemental analysis and IR spectroscopy. Their molecular structures were determined by single-crystal X-ray diffraction analysis. Thermal stability of compound <b>1</b> was studied by thermogravimetric analysis.</p>\",\"PeriodicalId\":756,\"journal\":{\"name\":\"Russian Chemical Bulletin\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":1.7000,\"publicationDate\":\"2024-07-26\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Russian Chemical Bulletin\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://doi.org/10.1007/s11172-024-4275-x\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Russian Chemical Bulletin","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1007/s11172-024-4275-x","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Two-dimensional coordination polymer of ytterbium(ii) with a 1,3-bis(pyridin-4-yl)propane linker
The reaction of the complex [(dpp-bian)2−Yb2+(THF)4] (dpp-bian is 1,2-bis[(2,6-diisopropylphenyl)imino]acenaphthene) with two molar equivalents of 1,3-bis(pyridin-4-yl)propane (bpp) in tetrahydrofuran (THF) afforded the 2D coordination polymer [{(dpp-bian)Yb(bpp)2} • 3 THF]n (1). The reaction of [(dpp-bian)2−Yb2+(DME)2] with phenazine (phz) gave the dimeric complex [{(dpp-bian)Yb(DME)}2(μ-η3:η3-phz)] • 2 DME (2), in which two cationic {(dpp-bian)Yb(DME)} units are connected via a bridging phenazine dianion. Compounds 1 and 2 were characterized by elemental analysis and IR spectroscopy. Their molecular structures were determined by single-crystal X-ray diffraction analysis. Thermal stability of compound 1 was studied by thermogravimetric analysis.
期刊介绍：
Publishing nearly 500 original articles a year, by leading Scientists from Russia and throughout the world, Russian Chemical Bulletin is a prominent international journal. The coverage of the journal spans practically all areas of fundamental chemical research and is presented in five sections:
General and Inorganic Chemistry;
Physical Chemistry;
Organic Chemistry;
Organometallic Chemistry;
Chemistry of Natural Compounds and Bioorganic Chemistry.
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