V. I. Filyakova, N. S. Boltacheva, M. G. Pervova, V. N. Charushin
{"title":"4′-trifluoromethyl- 和 4′-difluoromethyl-2,2′:6′,2″-terpyridines 的合成","authors":"V. I. Filyakova, N. S. Boltacheva, M. G. Pervova, V. N. Charushin","doi":"10.1007/s11172-024-4288-5","DOIUrl":null,"url":null,"abstract":"<div><p>A new synthetic approach to 2,2′:6′,2″-terpyridines bearing the CF<sub>3</sub> and HCF<sub>2</sub> substituents at the C(4′) atoms that involved the reaction of lithium 3-polyfluoroalkyl-1,3-ketoenolates with ammonium acetate in glacial AcOH was developed.</p></div>","PeriodicalId":756,"journal":{"name":"Russian Chemical Bulletin","volume":"73 6","pages":"1709 - 1715"},"PeriodicalIF":1.7000,"publicationDate":"2024-07-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Synthesis of 4′-trifluoromethyl- and 4′-difluoromethyl-2,2′:6′,2″-terpyridines\",\"authors\":\"V. I. Filyakova, N. S. Boltacheva, M. G. Pervova, V. N. Charushin\",\"doi\":\"10.1007/s11172-024-4288-5\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>A new synthetic approach to 2,2′:6′,2″-terpyridines bearing the CF<sub>3</sub> and HCF<sub>2</sub> substituents at the C(4′) atoms that involved the reaction of lithium 3-polyfluoroalkyl-1,3-ketoenolates with ammonium acetate in glacial AcOH was developed.</p></div>\",\"PeriodicalId\":756,\"journal\":{\"name\":\"Russian Chemical Bulletin\",\"volume\":\"73 6\",\"pages\":\"1709 - 1715\"},\"PeriodicalIF\":1.7000,\"publicationDate\":\"2024-07-26\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Russian Chemical Bulletin\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s11172-024-4288-5\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Russian Chemical Bulletin","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1007/s11172-024-4288-5","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Synthesis of 4′-trifluoromethyl- and 4′-difluoromethyl-2,2′:6′,2″-terpyridines
A new synthetic approach to 2,2′:6′,2″-terpyridines bearing the CF3 and HCF2 substituents at the C(4′) atoms that involved the reaction of lithium 3-polyfluoroalkyl-1,3-ketoenolates with ammonium acetate in glacial AcOH was developed.
期刊介绍:
Publishing nearly 500 original articles a year, by leading Scientists from Russia and throughout the world, Russian Chemical Bulletin is a prominent international journal. The coverage of the journal spans practically all areas of fundamental chemical research and is presented in five sections:
General and Inorganic Chemistry;
Physical Chemistry;
Organic Chemistry;
Organometallic Chemistry;
Chemistry of Natural Compounds and Bioorganic Chemistry.