(η6-苯)氯化[(S)-2-(4-异丙基-4,5-二氢恶唑-2-基)苯酚]钌(II)

IUCrData Pub Date : 2024-07-01 DOI:10.1107/S241431462400720X
Monsuru T. Kelani , Alfred Muller , Koop Lammertsma
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引用次数: 0

摘要

标题化合物[Ru(C12H14NO2)Cl(η6-C6H6)]呈半三明治三脚架结构,在正交空间群 P212121 中结晶。炔基与 Ru 原子呈 η6 π 配位,中心距为 1.6590 (5) Å,(S)-2-(4-异丙基-4,5-二氢恶唑-2-基)苯酚螯合配体通过其 N 原子和苯酚 O 原子形成 86.88 (19)° 的咬合角。该配合物的假八面体几何结构由一个氯配体完成。光学纯双齿配体的配位使配合物具有以金属为中心的手性,其 Flack 参数为 -0.056。
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(η6-Benzene)­chlorido­[(S)-2-(4-isopropyl-4,5-di­hydro­oxazol-2-yl)phenolato]ruthenium(II)

The title compound, [Ru(C12H14NO2)Cl(η6-C6H6)], exhibits a half-sandwich tripod stand structure and crystallizes in the ortho­rhom­bic space group P212121. The arene group is η6 π-coordinated to the Ru atom with a centroid-to-metal distance of 1.6590 (5) Å, with the (S)-2-(4-isopropyl-4,5-di­hydro­oxazol-2-yl)phenolate chelate ligand forming a bite angle of 86.88 (19)° through its N and phenolate O atoms.

The title compound, [Ru(C12H14NO2)Cl(η6-C6H6)], exhibits a half-sandwich tripod stand structure and crystallizes in the ortho­rhom­bic space group P212121. The arene group is η6 π-coordinated to the Ru atom with a centroid-to-metal distance of 1.6590 (5) Å, with the (S)-2-(4-isopropyl-4,5-di­hydro­oxazol-2-yl)phenolate chelate ligand forming a bite angle of 86.88 (19)° through its N and phenolate O atoms. The pseudo-octa­hedral geometry assumed by the complex is completed by a chloride ligand. The coordination of the optically pure bidentate ligand induces metal centered chirality onto the complex with a Flack parameter of −0.056.

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3-(2-Hy-droxy-eth-yl)-1-(4-nitro-phen-yl)-1H-imidazol-3-ium bromide. 4'-(2-Meth-oxy-phen-yl)-2,2':6',2''-terpyridine. 3,5,6-Tri-chloro-pyridin-2-ol. 4-Amino-3,5-di-chloro-pyridine. Bis(azido-κN 1)bis-(2,2'-di-pyridyl-amine-κ2 N 1,N 1')iron(II) monohydrate.
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