在新型燃烧器中部分催化 NH3 和 NH3/N2 的 MILD 燃烧

IF 5.3 2区 工程技术 Q2 ENERGY & FUELS Proceedings of the Combustion Institute Pub Date : 2024-07-24 DOI:10.1016/j.proci.2024.105509
Tong Jiang, Yanjun Sun, Lingfeng Dai, Weihao Zeng, Yingju Yang, Chun Zou
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引用次数: 0

摘要

氨气(NH)因其含氢、不含碳、基础设施庞大、利用安全和储存时间长等特点,目前在能源领域备受关注。然而,由于层流火焰速度低和氮含量高,NH 燃烧通常具有火焰不稳定性低和氮氧化物排放量高的问题。NH 的部分催化裂解为提高燃烧稳定性提供了一种经济的策略。然而,这种策略的明显局限性包括氮氧化物排放量高。因此,NH 部分催化裂解的 MILD 燃烧是解决这一难题的绝佳方法。本研究开发了一种新型三金属催化剂(Fe、Co 和 Ni),并在新型燃烧器中进行了部分催化 NH 和 NH/N 的 MILD 燃烧。实验研究了 NH 转化率、N 添加量和 NH 功率对污染物排放的影响。对实验中观察到的部分催化 NH 和 NH/N 的 MILD 燃烧特性进行了数值模拟分析。
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MILD combustion of partially catalyzed NH3 and NH3/N2 in a novel burner
Ammonia (NH) is now attracting attention in the energy field due to its hydrogen-containing and carbon-free, vast infrastructure, safe utilization and longstanding storage. Nevertheless, NH combustion is usually associated with low flame instability and high NO emissions due to its low laminar flame speed and nitrogen content. The partial catalytic cracking of NH offers an economical strategy to improve combustion stability. However, the significant limitations of this strategy include high NO emissions. Therefore, the MILD combustion of partial catalytic cracking of NH is an excellent method to address the challenge. In this work, a novel trimetallic catalyst (Fe, Co, and Ni) was developed, and the MILD combustion of partially catalyzed NH and NH/N was performed in a novel burner. The effects of the NH conversion, N addition and NH power on pollutant emissions were experimental investigated. Numerical simulations were carried out to analyze the characteristics in the MILD combustion of partially catalyzed NH and NH/N observed in the experiments.
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来源期刊
Proceedings of the Combustion Institute
Proceedings of the Combustion Institute 工程技术-工程:化工
CiteScore
7.00
自引率
0.00%
发文量
420
审稿时长
3.0 months
期刊介绍: The Proceedings of the Combustion Institute contains forefront contributions in fundamentals and applications of combustion science. For more than 50 years, the Combustion Institute has served as the peak international society for dissemination of scientific and technical research in the combustion field. In addition to author submissions, the Proceedings of the Combustion Institute includes the Institute''s prestigious invited strategic and topical reviews that represent indispensable resources for emergent research in the field. All papers are subjected to rigorous peer review. Research papers and invited topical reviews; Reaction Kinetics; Soot, PAH, and other large molecules; Diagnostics; Laminar Flames; Turbulent Flames; Heterogeneous Combustion; Spray and Droplet Combustion; Detonations, Explosions & Supersonic Combustion; Fire Research; Stationary Combustion Systems; IC Engine and Gas Turbine Combustion; New Technology Concepts The electronic version of Proceedings of the Combustion Institute contains supplemental material such as reaction mechanisms, illustrating movies, and other data.
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