高碘酸氧化喹啉类生物碱 Bucharaine、Foliosidine、Evoxine 和 Dubinidine

IF 0.8 4区化学 Q4 CHEMISTRY, MEDICINAL Chemistry of Natural Compounds Pub Date : 2024-08-07 DOI:10.1007/s10600-024-04410-7

Sh. N. Zhurakulov, E. A. Bainazarov, V. I. Vinogradova, M. A. Eshonov, K. K. Turgunov, B. Tashkhodzhaev, Zh. K. Namazbaeva

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引用次数: 0

摘要

研究了周期酸对喹啉生物碱 bucharaine、foliosidine、evoxine 和 dubinidine 氧化作用的影响，这种影响与它们的结构和反应条件有关。结果表明，稀水溶液中的高碘酸能形成稳定的高碘二醇。使用大量过量的 HIO4 会形成 gem-diols 和醛。在 MeOH 水溶液中获得了 O-甲基衍生物。

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Oxidation of Quinoline Alkaloids Bucharaine, Foliosidine, Evoxine, and Dubinidine by Periodic Acid

The effect of periodic acid on oxidation of the quinoline alkaloids bucharaine, foliosidine, evoxine, and dubinidine was studied as a function of their structures and the reaction conditions. Periodic acid in dilute aqueous solutions was shown to form stable gem-diols. The use of a large excess of HIO₄ formed gem-diols and aldehydes. O-Methyl derivatives were obtained in aqueous MeOH solutions.

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来源期刊

Chemistry of Natural Compounds 化学-有机化学

CiteScore

1.40

自引率

25.00%

发文量

265

审稿时长

7.8 months

期刊介绍： Chemistry of Natural Compounds publishes reviews and general articles about the structure of different classes of natural compounds, the chemical characteristics of botanical families, genus, and species, to establish the comparative laws and connection between physiological activity and the structure of substances.