{"title":"能源变压器冷却油中抗氧化剂的分子相互作用:介电和模拟研究","authors":"","doi":"10.1016/j.molliq.2024.125795","DOIUrl":null,"url":null,"abstract":"<div><p>This research paper presents experimental and theoretical findings concerning the blending of mineral oil and vegetable oils, both with and without antioxidants. The study analyses a variety of parameters for different blends of mineral and vegetable oils, including breakdown voltage, ageing resistance, dielectric constant, viscosity, dissipation factor, surface tension, flash point, and fire point. The study was further extended to investigate the effects of varying the amount of antioxidants added to mineral oil blends with different vegetable oils. The best transformer insulating solution is found by extensive analyses that include measurements of breakdown voltage, flash point, fire point, and surface tension. This blends’ properties with antioxidant are either better than pure mineral oil or comparable to mineral oil. Density functional theory (DFT) analyses the molecular structure and dipole moment of an antioxidant. Molecular dynamics simulation method (MD) analysis of the average water residual time – periods of an antioxidant will show the stability of H-bond interactions. The primary objective of this experiment is to unveil a novel liquid-insulating material that not only excels in dielectric performance but also aligns with environmentally friendly practices.</p></div>","PeriodicalId":371,"journal":{"name":"Journal of Molecular Liquids","volume":null,"pages":null},"PeriodicalIF":5.3000,"publicationDate":"2024-08-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Molecular interactions of the antioxidant in the coolant oil for energy transformers: Dielectric and simulation studies\",\"authors\":\"\",\"doi\":\"10.1016/j.molliq.2024.125795\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>This research paper presents experimental and theoretical findings concerning the blending of mineral oil and vegetable oils, both with and without antioxidants. The study analyses a variety of parameters for different blends of mineral and vegetable oils, including breakdown voltage, ageing resistance, dielectric constant, viscosity, dissipation factor, surface tension, flash point, and fire point. The study was further extended to investigate the effects of varying the amount of antioxidants added to mineral oil blends with different vegetable oils. The best transformer insulating solution is found by extensive analyses that include measurements of breakdown voltage, flash point, fire point, and surface tension. This blends’ properties with antioxidant are either better than pure mineral oil or comparable to mineral oil. Density functional theory (DFT) analyses the molecular structure and dipole moment of an antioxidant. Molecular dynamics simulation method (MD) analysis of the average water residual time – periods of an antioxidant will show the stability of H-bond interactions. The primary objective of this experiment is to unveil a novel liquid-insulating material that not only excels in dielectric performance but also aligns with environmentally friendly practices.</p></div>\",\"PeriodicalId\":371,\"journal\":{\"name\":\"Journal of Molecular Liquids\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":5.3000,\"publicationDate\":\"2024-08-16\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Molecular Liquids\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0167732224018543\",\"RegionNum\":2,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Molecular Liquids","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0167732224018543","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
引用次数: 0
摘要
本研究论文介绍了有关矿物油和植物油(含抗氧化剂和不含抗氧化剂)混合的实验和理论研究结果。研究分析了矿物油和植物油不同混合物的各种参数,包括击穿电压、抗老化性、介电常数、粘度、耗散因子、表面张力、闪点和燃点。研究还进一步扩展,调查了矿物油与不同植物油混合物中抗氧化剂添加量变化的影响。通过对击穿电压、闪点、燃点和表面张力的测量等大量分析,找到了最佳的变压器绝缘解决方案。这种含有抗氧化剂的混合物的性能要么优于纯矿物油,要么与矿物油相当。密度泛函理论(DFT)分析了抗氧化剂的分子结构和偶极矩。分子动力学模拟方法(MD)分析抗氧化剂的平均水残留时间-周期,可显示 H 键相互作用的稳定性。本实验的主要目的是揭示一种新型液体绝缘材料,它不仅具有出色的介电性能,而且符合环保要求。
Molecular interactions of the antioxidant in the coolant oil for energy transformers: Dielectric and simulation studies
This research paper presents experimental and theoretical findings concerning the blending of mineral oil and vegetable oils, both with and without antioxidants. The study analyses a variety of parameters for different blends of mineral and vegetable oils, including breakdown voltage, ageing resistance, dielectric constant, viscosity, dissipation factor, surface tension, flash point, and fire point. The study was further extended to investigate the effects of varying the amount of antioxidants added to mineral oil blends with different vegetable oils. The best transformer insulating solution is found by extensive analyses that include measurements of breakdown voltage, flash point, fire point, and surface tension. This blends’ properties with antioxidant are either better than pure mineral oil or comparable to mineral oil. Density functional theory (DFT) analyses the molecular structure and dipole moment of an antioxidant. Molecular dynamics simulation method (MD) analysis of the average water residual time – periods of an antioxidant will show the stability of H-bond interactions. The primary objective of this experiment is to unveil a novel liquid-insulating material that not only excels in dielectric performance but also aligns with environmentally friendly practices.
期刊介绍:
The journal includes papers in the following areas:
– Simple organic liquids and mixtures
– Ionic liquids
– Surfactant solutions (including micelles and vesicles) and liquid interfaces
– Colloidal solutions and nanoparticles
– Thermotropic and lyotropic liquid crystals
– Ferrofluids
– Water, aqueous solutions and other hydrogen-bonded liquids
– Lubricants, polymer solutions and melts
– Molten metals and salts
– Phase transitions and critical phenomena in liquids and confined fluids
– Self assembly in complex liquids.– Biomolecules in solution
The emphasis is on the molecular (or microscopic) understanding of particular liquids or liquid systems, especially concerning structure, dynamics and intermolecular forces. The experimental techniques used may include:
– Conventional spectroscopy (mid-IR and far-IR, Raman, NMR, etc.)
– Non-linear optics and time resolved spectroscopy (psec, fsec, asec, ISRS, etc.)
– Light scattering (Rayleigh, Brillouin, PCS, etc.)
– Dielectric relaxation
– X-ray and neutron scattering and diffraction.
Experimental studies, computer simulations (MD or MC) and analytical theory will be considered for publication; papers just reporting experimental results that do not contribute to the understanding of the fundamentals of molecular and ionic liquids will not be accepted. Only papers of a non-routine nature and advancing the field will be considered for publication.