封面:五配位铁酞菁在各种酸性溶液中发生氧还原反应的电化学评价(ChemElectroChem 16/2024)

IF 3.5 4区 化学 Q2 ELECTROCHEMISTRY ChemElectroChem Pub Date : 2024-08-19 DOI:10.1002/celc.202481601
César Zúñiga Loyola, Nicolás Troncoso, Angélica Gatica Caro, Federico Tasca
{"title":"封面:五配位铁酞菁在各种酸性溶液中发生氧还原反应的电化学评价(ChemElectroChem 16/2024)","authors":"César Zúñiga Loyola,&nbsp;Nicolás Troncoso,&nbsp;Angélica Gatica Caro,&nbsp;Federico Tasca","doi":"10.1002/celc.202481601","DOIUrl":null,"url":null,"abstract":"<p><b>The front cover</b> picture represents a meta–air battery composed of a metal anode and a graphite cathode modified with pyridine penta-coordinated Fe phthalocyanine, which is an extremely active catalyst for the oxygen reduction reaction when the NaOH supporting electrolyte is used. When in the presence of other electrolytes, the activity of the catalyst decreases as the Fe active sites are poisoned by the interaction with the anions. Therefore, batteries with lower power density are obtained if in the presence of Cl<sup>−</sup>&gt;Br<sup>−</sup>&gt;HSO<sub>4</sub><sup>−</sup>&gt; ClO<sub>4</sub><sup>−</sup>&gt;NO<sub>3</sub><sup>−</sup>&gt;OH<sup>−</sup>. More information can be found in the Research Article by Federico Tasca and co-workers (DOI: 10.1002/celc.202400186).\n <figure>\n <div><picture>\n <source></source></picture><p></p>\n </div>\n </figure>\n </p>","PeriodicalId":142,"journal":{"name":"ChemElectroChem","volume":"11 16","pages":""},"PeriodicalIF":3.5000,"publicationDate":"2024-08-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/celc.202481601","citationCount":"0","resultStr":"{\"title\":\"Front Cover: Electrochemical Evaluation of Penta-Coordinated Fe Phthalocyanine During the Oxygen Reduction Reaction in Various Acidic Solutions (ChemElectroChem 16/2024)\",\"authors\":\"César Zúñiga Loyola,&nbsp;Nicolás Troncoso,&nbsp;Angélica Gatica Caro,&nbsp;Federico Tasca\",\"doi\":\"10.1002/celc.202481601\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p><b>The front cover</b> picture represents a meta–air battery composed of a metal anode and a graphite cathode modified with pyridine penta-coordinated Fe phthalocyanine, which is an extremely active catalyst for the oxygen reduction reaction when the NaOH supporting electrolyte is used. When in the presence of other electrolytes, the activity of the catalyst decreases as the Fe active sites are poisoned by the interaction with the anions. Therefore, batteries with lower power density are obtained if in the presence of Cl<sup>−</sup>&gt;Br<sup>−</sup>&gt;HSO<sub>4</sub><sup>−</sup>&gt; ClO<sub>4</sub><sup>−</sup>&gt;NO<sub>3</sub><sup>−</sup>&gt;OH<sup>−</sup>. More information can be found in the Research Article by Federico Tasca and co-workers (DOI: 10.1002/celc.202400186).\\n <figure>\\n <div><picture>\\n <source></source></picture><p></p>\\n </div>\\n </figure>\\n </p>\",\"PeriodicalId\":142,\"journal\":{\"name\":\"ChemElectroChem\",\"volume\":\"11 16\",\"pages\":\"\"},\"PeriodicalIF\":3.5000,\"publicationDate\":\"2024-08-19\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://onlinelibrary.wiley.com/doi/epdf/10.1002/celc.202481601\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"ChemElectroChem\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://onlinelibrary.wiley.com/doi/10.1002/celc.202481601\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"ELECTROCHEMISTRY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"ChemElectroChem","FirstCategoryId":"92","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/celc.202481601","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"ELECTROCHEMISTRY","Score":null,"Total":0}
引用次数: 0

摘要

封面图片展示的是由金属阳极和石墨阴极组成的元空气电池,石墨阴极由吡啶五配位铁酞菁改性而成,当使用 NaOH 支持电解质时,铁酞菁是氧还原反应中极为活跃的催化剂。当存在其他电解质时,由于铁的活性位点与阴离子相互作用而中毒,催化剂的活性就会降低。因此,如果存在 Cl->Br->HSO4->ClO4->NO3->OH-,电池的功率密度就会降低。更多信息,请参阅 Federico Tasca 及其合作者的研究文章(DOI: 10.1002/celc.202400186)。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

摘要图片

查看原文
分享 分享
微信好友 朋友圈 QQ好友 复制链接
本刊更多论文
Front Cover: Electrochemical Evaluation of Penta-Coordinated Fe Phthalocyanine During the Oxygen Reduction Reaction in Various Acidic Solutions (ChemElectroChem 16/2024)

The front cover picture represents a meta–air battery composed of a metal anode and a graphite cathode modified with pyridine penta-coordinated Fe phthalocyanine, which is an extremely active catalyst for the oxygen reduction reaction when the NaOH supporting electrolyte is used. When in the presence of other electrolytes, the activity of the catalyst decreases as the Fe active sites are poisoned by the interaction with the anions. Therefore, batteries with lower power density are obtained if in the presence of Cl>Br>HSO4> ClO4>NO3>OH. More information can be found in the Research Article by Federico Tasca and co-workers (DOI: 10.1002/celc.202400186).

求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
ChemElectroChem
ChemElectroChem ELECTROCHEMISTRY-
CiteScore
7.90
自引率
2.50%
发文量
515
审稿时长
1.2 months
期刊介绍: ChemElectroChem is aimed to become a top-ranking electrochemistry journal for primary research papers and critical secondary information from authors across the world. The journal covers the entire scope of pure and applied electrochemistry, the latter encompassing (among others) energy applications, electrochemistry at interfaces (including surfaces), photoelectrochemistry and bioelectrochemistry.
期刊最新文献
Front Cover: Electrocatalytic Performance and Kinetic Behavior of Anion-Intercalated Borate-Based NiFe LDH in Alkaline OER (ChemElectroChem 22/2024) Cover Feature: Cost-Effective Solutions for Lithium-Ion Battery Manufacturing: Comparative Analysis of Olefine and Rubber-Based Alternative Binders for High-Energy Ni-Rich NCM Cathodes (ChemElectroChem 21/2024) Front Cover: High-performance Porous Electrodes for Flow Batteries: Improvements of Specific Surface Areas and Reaction Kinetics (ChemElectroChem 21/2024) Lithium Doping Enhances the Aqueous Zinc Ion Storage Performance of V3O7 ⋅ H2O Nanorods Annihilation Electrochemiluminescence Triggered by Bipolar Electrochemistry
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
已复制链接
已复制链接
快去分享给好友吧!
我知道了
×
扫码分享
扫码分享
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1