{"title":"共价金属催化或介导的炔类氧化杂芳基化反应","authors":"","doi":"10.1016/j.tetlet.2024.155249","DOIUrl":null,"url":null,"abstract":"<div><p>This review explores the coinage metal-catalyzed or-mediated oxidative heteroarylation of activated arenes or arenes possessing DG and focuses on the role of directing groups in influencing the efficiency and selectivity of product conversions. This leads to the construction of new C<img>C and C<img>N bonds. The synthesized heteroaryl products by this method are part of the many natural products, and have significance in pharmaceuticals, agrochemicals, and advanced material chemistry.</p></div>","PeriodicalId":438,"journal":{"name":"Tetrahedron Letters","volume":null,"pages":null},"PeriodicalIF":1.5000,"publicationDate":"2024-08-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Coinage metal-catalyzed or-mediated oxidative heteroarylation of arenes\",\"authors\":\"\",\"doi\":\"10.1016/j.tetlet.2024.155249\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>This review explores the coinage metal-catalyzed or-mediated oxidative heteroarylation of activated arenes or arenes possessing DG and focuses on the role of directing groups in influencing the efficiency and selectivity of product conversions. This leads to the construction of new C<img>C and C<img>N bonds. The synthesized heteroaryl products by this method are part of the many natural products, and have significance in pharmaceuticals, agrochemicals, and advanced material chemistry.</p></div>\",\"PeriodicalId\":438,\"journal\":{\"name\":\"Tetrahedron Letters\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":1.5000,\"publicationDate\":\"2024-08-18\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Tetrahedron Letters\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0040403924003447\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"CHEMISTRY, ORGANIC\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Tetrahedron Letters","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0040403924003447","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, ORGANIC","Score":null,"Total":0}
引用次数: 0
摘要
本综述探讨了共价金属催化或介导的活化烯烃或具有 DG 的烯烃的氧化杂芳基化反应,并重点研究了定向基团在影响产物转化效率和选择性方面的作用。这导致了新的 CC 和 CN 键的形成。用这种方法合成的杂芳基产品是许多天然产品的一部分,在医药、农用化学品和先进材料化学方面具有重要意义。
Coinage metal-catalyzed or-mediated oxidative heteroarylation of arenes
This review explores the coinage metal-catalyzed or-mediated oxidative heteroarylation of activated arenes or arenes possessing DG and focuses on the role of directing groups in influencing the efficiency and selectivity of product conversions. This leads to the construction of new CC and CN bonds. The synthesized heteroaryl products by this method are part of the many natural products, and have significance in pharmaceuticals, agrochemicals, and advanced material chemistry.
期刊介绍:
Tetrahedron Letters provides maximum dissemination of outstanding developments in organic chemistry. The journal is published weekly and covers developments in techniques, structures, methods and conclusions in experimental and theoretical organic chemistry. Rapid publication of timely and significant research results enables researchers from all over the world to transmit quickly their new contributions to large, international audiences.