Innenrücktitelbild：揭示高核度异金属团簇组装背后的交织因素（Angew.）

Angewandte Chemie Pub Date : 2024-09-01 DOI:10.1002/ange.202414386

Dr. Na Xu, Dr. Wanmin Chen, Dr. Jun Miao, Dr. Yousong Ding, Prof. Zhiping Zheng

{"title":"Innenrücktitelbild：揭示高核度异金属团簇组装背后的交织因素（Angew.）","authors":"Dr. Na Xu, Dr. Wanmin Chen, Dr. Jun Miao, Dr. Yousong Ding, Prof. Zhiping Zheng","doi":"10.1002/ange.202414386","DOIUrl":null,"url":null,"abstract":"Two structurally intricate heterometallic clusters with cores featuring multiple Platonic and Archimedean polyhedra were synthesized by ligand-controlled co-hydrolysis of Ni2+ and Dy3+ ions, as reported by Zhiping Zheng et al. in their Research Article (e202409109). Adjusting the amount of hydrolysis-promoting base and the reaction temperature and duration afforded selectively the kinetic and thermodynamic species, respectively with a Dy112Ni76 and a Dy52Ni44 core.\n <figure>\n <div><picture>\n <source></source></picture>\n </div>\n </figure>\n ","PeriodicalId":7803,"journal":{"name":"Angewandte Chemie","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"2024-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/ange.202414386","citationCount":"0","resultStr":"{\"title\":\"Innenrücktitelbild: Unraveling the Intertwining Factors Underlying the Assembly of High-Nuclearity Heterometallic Clusters (Angew. Chem. 37/2024)\",\"authors\":\"Dr. Na Xu, Dr. Wanmin Chen, Dr. Jun Miao, Dr. Yousong Ding, Prof. Zhiping Zheng\",\"doi\":\"10.1002/ange.202414386\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Two structurally intricate heterometallic clusters with cores featuring multiple Platonic and Archimedean polyhedra were synthesized by ligand-controlled co-hydrolysis of Ni2+ and Dy3+ ions, as reported by Zhiping Zheng et al. in their Research Article (e202409109). Adjusting the amount of hydrolysis-promoting base and the reaction temperature and duration afforded selectively the kinetic and thermodynamic species, respectively with a Dy112Ni76 and a Dy52Ni44 core.\\n <figure>\\n <div><picture>\\n <source></source></picture>\\n </div>\\n </figure>\\n \",\"PeriodicalId\":7803,\"journal\":{\"name\":\"Angewandte Chemie\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2024-09-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://onlinelibrary.wiley.com/doi/epdf/10.1002/ange.202414386\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Angewandte Chemie\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://onlinelibrary.wiley.com/doi/10.1002/ange.202414386\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Angewandte Chemie","FirstCategoryId":"1085","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/ange.202414386","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}

引用次数: 0

摘要

郑志平等人在其研究文章（e202409109）中报道了通过配体控制Ni2+和Dy3+离子的共水解作用合成了两种结构复杂的异金属簇，其核具有多个柏拉图和阿基米德多面体。通过调节水解促进碱的用量、反应温度和持续时间，可以选择性地得到分别以 Dy112Ni76 和 Dy52Ni44 为核心的动力学和热力学物种。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

摘要图片

查看原文

微信好友朋友圈 QQ好友复制链接

本刊更多论文

Innenrücktitelbild: Unraveling the Intertwining Factors Underlying the Assembly of High-Nuclearity Heterometallic Clusters (Angew. Chem. 37/2024)

Two structurally intricate heterometallic clusters with cores featuring multiple Platonic and Archimedean polyhedra were synthesized by ligand-controlled co-hydrolysis of Ni²⁺ and Dy³⁺ ions, as reported by Zhiping Zheng et al. in their Research Article (e202409109). Adjusting the amount of hydrolysis-promoting base and the reaction temperature and duration afforded selectively the kinetic and thermodynamic species, respectively with a Dy₁₁₂Ni₇₆ and a Dy₅₂Ni₄₄ core.