二苯并呋喃杂环:咔唑、二苯并呋喃和二苯并噻吩合成的十年更新。

IF 7 2区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY Chemical record Pub Date : 2024-09-06 DOI:10.1002/tcr.202400078
Anjana Sreekumar, Ajil R. Nair, C. Raksha, S. Gopika, S. Padmanabhan, R. Gopalakrishna Pai, Dr. Akhil Sivan
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引用次数: 0

摘要

多环杂环是各种天然产品、药物、肥料和先进材料中最常见和最重要的结构基团。由于其在生物活性化合物和材料化学中的广泛应用,功能化二苯杂环化合物,尤其是二苯并呋喃、二苯并噻吩和咔唑衍生物,一直以来都备受关注。科学家们对阐明开发这些工业必需化合物的更有效技术尤其感兴趣。利用高效的过渡金属催化策略以及经济的无金属反应条件,可以快速合成二苯并融合杂环。本综述详细概述了最新的重要合成技术,包括金属催化和无金属催化技术,以生产这些具有重要工业意义和药用价值的二苯并融合杂环化合物。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

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Dibenzo-Fused Heterocycles: A Decade Update on the Syntheses of Carbazole, Dibenzofuran, and Dibenzothiophene

Polycyclic heterocycles are the most common and critical structural motifs found in a variety of natural products, medicines, fertilizers, and advanced materials. Because of their widespread use in biologically active compounds and material chemistry, functionalised dibenzo heterocyclic compounds, especially dibenzofuran, dibenzothiophene, and carbazole derivatives, garnered much attention over time. Scientists are especially interested in elucidating more efficient techniques for developing these industrially essential compounds. Dibenzo-fused heterocycles can rapidly be synthesised using highly efficient transition metal-catalysed strategies as well as by economic metal-free reaction conditions. This review includes a detailed overview of the most recent significant synthetic techniques, both metal-catalysed and metal-free, to produce these industrially significant and medicinally important dibenzo-fused heterocycles.

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来源期刊
Chemical record
Chemical record 化学-化学综合
CiteScore
11.00
自引率
3.00%
发文量
188
审稿时长
>12 weeks
期刊介绍: The Chemical Record (TCR) is a "highlights" journal publishing timely and critical overviews of new developments at the cutting edge of chemistry of interest to a wide audience of chemists (2013 journal impact factor: 5.577). The scope of published reviews includes all areas related to physical chemistry, analytical chemistry, inorganic chemistry, organic chemistry, polymer chemistry, materials chemistry, bioorganic chemistry, biochemistry, biotechnology and medicinal chemistry as well as interdisciplinary fields. TCR provides carefully selected highlight papers by leading researchers that introduce the author''s own experimental and theoretical results in a framework designed to establish perspectives with earlier and contemporary work and provide a critical review of the present state of the subject. The articles are intended to present concise evaluations of current trends in chemistry research to help chemists gain useful insights into fields outside their specialization and provide experts with summaries of recent key developments.
期刊最新文献
Recent Advances in Selenium-Mediated Redox Functional Group Interconversions. From Lithium-Ion to Sodium-Ion Batteries for Sustainable Energy Storage: A Comprehensive Review on Recent Research Advancements and Perspectives. Recent Progress in Steroid C(sp3)-H Functionalization. N-Heterocyclic Carbene Catalyzed Reactions Involving Acetylenic Breslow and/or Acylazolium as Key Intermediates. Recent Advances of C-S Coupling Reaction of (Hetero)Arenes by C-H Functionalization.
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