基于 5-苯基-2,2'-联吡啶且 C6 位有二乙烯三氨基四乙酸残基的钐(III)配合物：合成、晶体结构和光物理性质

IF 1.1 3区化学 Q4 CHEMISTRY, INORGANIC & NUCLEAR Russian Journal of Coordination Chemistry Pub Date : 2024-08-15 DOI:10.1134/S1070328424600268

A. P. Krinochkin, S. E. Vatolina, V. S. Gaviko, I. A. Litvinov, M. I. Valieva, Ya. K. Shtaitz, S. S. Rybakova, D. S. Kopchuk, G. V. Zyryanov, V. L. Rusinov

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摘要

摘要合成了 5-苯基-2,2'-联吡啶的新型钐络合物[(L2)Sm2Na5(H2О)9(C2O4)]n (I)。通过 XRD（CIF 文件 CCDC 编号 2217968）研究了复合物 I 的结构。发现晶体中的配合物是一种一维配位聚合物，2,2'-联吡啶片段不与 Sm3+ 阳离子螯合。该复合物的特点是在加入过量锌阳离子时会发光。

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Samarium(III) Complex Based on 5-Phenyl-2,2'-bipyridine with the Diethylenetriaminotetraacetic Acid Residue in the C6 Position: Synthesis, Crystal Structure, and Photophysical Properties

New samarium complex of 5-phenyl-2,2'-bipyridine with the diethylenetriaminotetraacetic acid (DTTA) residue in the C6 position, [(L₂)Sm₂Na₅(H₂О)₉(C₂O₄)]_n (I), is synthesized. The structure of complex I is studied by XRD (CIF file CCDC no. 2217968). The complex in the crystal is found to be a one-dimensional coordination polymer, and the 2,2'-bipyridine fragments do not chelate the Sm³⁺ cation. The complex is characterized by a luminescence response to the addition of an excess of zinc cations.

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来源期刊

Russian Journal of Coordination Chemistry 化学-无机化学与核化学

CiteScore

2.40

自引率

15.80%

发文量

审稿时长

7.2 months

期刊介绍： Russian Journal of Coordination Chemistry is a journal that publishes reviews, original papers, and short communications on all aspects of theoretical and experimental coordination chemistry. Modern coordination chemistry is an interdisciplinary science that makes a bridge between inorganic, organic, physical, analytical, and biological chemistry.