椰子纤维增强热塑性淀粉/聚(己二酸丁二醇酯-对苯二甲酸酯)复合材料的机械性能和热性能研究

IF 2.7 3区 化学 Q2 POLYMER SCIENCE Journal of Applied Polymer Science Pub Date : 2024-09-04 DOI:10.1002/app.56206
Xianggang Tang, Jianwei Tan, Yongxiang Hu, Chengzhuang Su, Zhekun Liu, Chuncheng Wei, Shuhua Dong, Fantao Meng
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引用次数: 0

摘要

本研究通过熔融混合和注射成型制备了一种新型可生物降解的棕纤维(CF)增强热塑性淀粉(TPS)和聚己二酸丁二醇酯(PBAT)复合材料(CF/TPS/PBAT),TPS 与 PBAT 的重量比为 70:30,CF 的添加量分别为 5、10、15 和 20 wt%。研究了纤维含量和纤维表面改性对所制备生物复合材料机械性能和热性能的影响。纤维的加入有效提高了 TPS/PBAT 共混物的力学性能和热性能。由于碱处理后纤维表面的半纤维素和杂质被去除,增强了纤维的界面粘附性,从而提高了纤维与基体的相容性。与 TPS/PBAT 混合物相比,碱处理后 20 wt% 的 CFs 拉伸强度提高了 393%,弯曲强度提高了 536%。热分析表明,复合材料的热稳定性、储存模量和玻璃化转变温度随着纤维含量的增加而提高。这项工作对生物可降解材料的开发具有重要意义。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

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Study on mechanical and thermal properties of coir fibers reinforced thermoplastic starch/poly(butylene adipate-co-terephthalate) composites

In this study, a novel biodegradable coir fiber (CF) reinforced thermoplastic starch (TPS) and poly(butylene adipate-co-terephthalate) (PBAT) composites (CF/TPS/PBAT) with a constant TPS: PBAT weight ratio of 70:30 and 5, 10, 15, and 20 wt% additions of CF were prepared by the melt blending and injection molding. The effects of fiber content and fiber surface modification on the mechanical and thermal properties of the prepared biocomposites were investigated. The incorporation of fibers effectively enhanced the mechanical and thermal properties of TPS/PBAT blends. Due to the removal of hemicellulose and impurities on the fiber surface after alkali treatment, the interfacial adhesion of the fiber was enhanced, thus improving the compatibility between the fibers and the matrix. At 20 wt% CFs with alkali treatment, the tensile strength exhibited 393% improvement and flexural strength exhibited 536% improvement over TPS/PBAT blends. Thermal analysis showed that the thermal stability, storage modulus, and glass transition temperature of the composites increased with the increase of fiber content. This work is significant for the development of biodegradable materials.

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来源期刊
Journal of Applied Polymer Science
Journal of Applied Polymer Science 化学-高分子科学
CiteScore
5.70
自引率
10.00%
发文量
1280
审稿时长
2.7 months
期刊介绍: The Journal of Applied Polymer Science is the largest peer-reviewed publication in polymers, #3 by total citations, and features results with real-world impact on membranes, polysaccharides, and much more.
期刊最新文献
Editorial Board, Aims & Scope, Table of Contents Editorial Board, Aims & Scope, Table of Contents Editorial Board, Aims & Scope, Table of Contents Editorial Board, Aims & Scope, Table of Contents Cover Image, Volume 141, Issue 43
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