作为碳-聚合物复合双极板的新型次导电填料的碳雪凝胶

IF 5.1 4区 材料科学 Q2 ELECTROCHEMISTRY Batteries & Supercaps Pub Date : 2024-08-23 DOI:10.1002/batt.202400316
Priyanka Sharma, Abdurrahman Bilican, Wolfgang Schmidt, Olof Gutowski, Ann-Christin Dippel, Kimberley Matschuk, Lukas Kopietz, Claudia Weidenthaler
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引用次数: 0

摘要

目前的研究探索了碳异凝胶作为双极板导电填料的潜力。复合材料包括作为主要导电填料的石墨和作为粘合剂的聚丙烯。碳异凝胶作为次要导电填料被引入,其性能与商用炭黑进行了比较。这两种纳米碳在微观结构、质地和表面碳化学性质方面都有相似之处。通面电导率测量结果表明,用其中一种纳米填料取代一部分石墨后,电导率会增强。利用基于 X 射线衍射和相位对比的计算机断层扫描技术对板材进行的横截面分析表明,观察到的导电性差异源于生产过程中残留空气的减少和次要填料颗粒的分布。鉴于碳异凝胶与参考纳米填料之间的相似性,本研究提出了采用碳异凝胶作为导电双极板填料的创新概念。
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Carbon Xerogel as a Novel Minor Conductive Filler for Carbon‐Polymer Composite Bipolar Plates
The current research explores the potential of carbon xerogel as a conductive filler in bipolar plates. The composites comprise graphite as the primary conductive filler and polypropylene as the binder. Carbon xerogel is introduced as a minor conductive filler, and its performance is compared with commercial carbon black. Both nanocarbons exhibit resemblances in microstructure, texture, and surface carbon chemistry. Through‐plane conductivity measurements reveal enhanced electrical conductivity upon replacing a fraction of graphite with either nanofiller. Cross‐sectional analyses of the plates employing computed tomography based on X‐ray diffraction and phase contrasts indicate that the observed electrical conductivity difference stems from reduced trapped air during production and the distribution of the minor filler particles. Given the similarities between carbon xerogel and the reference nanofiller, this study introduces the innovative concept of employing carbon xerogel as a filler for conductive bipolar plates.
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来源期刊
CiteScore
8.60
自引率
5.30%
发文量
223
期刊介绍: Electrochemical energy storage devices play a transformative role in our societies. They have allowed the emergence of portable electronics devices, have triggered the resurgence of electric transportation and constitute key components in smart power grids. Batteries & Supercaps publishes international high-impact experimental and theoretical research on the fundamentals and applications of electrochemical energy storage. We support the scientific community to advance energy efficiency and sustainability.
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