在立体选择性合成 1Z,5Z,9Z,13Z-四烯过程中钛催化 (Z)-1,2,6 三烯的同环镁化反应

IF 1.7 4区化学 Q3 CHEMISTRY, MULTIDISCIPLINARY Russian Chemical Bulletin Pub Date : 2024-08-31 DOI:10.1007/s11172-024-4309-4

E. Kh. Makarova, A. A. Makarov

引用次数: 0

摘要

在钛催化的末端 1,2 二烯同环镁反应的基础上，开发出了一种高产率和高立体选择性合成 1Z,5Z,9Z,13Z-四烯的有效方法。此外，还阐述了一种合成含有 Z 双键取代基的烯烃的新方法。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

查看原文

微信好友朋友圈 QQ好友复制链接

本刊更多论文

Ti-catalyzed homocyclomagnesiation of (Z)-1,2,6-trienes in the stereoselective synthesis of 1Z,5Z,9Z,13Z-tetraenes

On the basis of the Ti-catalyzed homocyclomagnesiation of terminal 1,2-dienes, an effective method for the synthesis of 1Z,5Z,9Z,13Z-tetraenes in high yields and high stereoselectivity has been developed. A new approach to the synthesis of allenes with substituents containing Z-double bonds has been elaborated.

求助全文

通过发布文献求助，成功后即可免费获取论文全文。去求助

来源期刊

Russian Chemical Bulletin 化学-化学综合

CiteScore

2.70

自引率

47.10%

发文量

257

审稿时长

3-8 weeks

期刊介绍： Publishing nearly 500 original articles a year, by leading Scientists from Russia and throughout the world, Russian Chemical Bulletin is a prominent international journal. The coverage of the journal spans practically all areas of fundamental chemical research and is presented in five sections: General and Inorganic Chemistry; Physical Chemistry; Organic Chemistry; Organometallic Chemistry; Chemistry of Natural Compounds and Bioorganic Chemistry.

期刊最新文献

Dye-sensitized solar cells based on D—A—π—A′ structures with a 4H-cyclopenta[2,1-b:3,4-b′]dithiophene fragment containing branched alkyl groups Titanocene-catalyzed selective synthesis of 2,4-dialkyl-6-(2-methoxyethyl)pyridines by the reaction of terminal acetylenes with 3-methoxypropionitrile New europium complexes of C(6)-DTTA-appended 5-aryl-2,2′-bipyridines: synthesis, luminescence, and evaluation of their activity against cell culture Salt of dysprosium(iii) tetrakis(hexafluoroacetylacetonate) with 1,1′-dimethyl-4,4′-bipyridinium as a new single-ion magnet The first non-symmetrically substituted conjugates of bispidine with monoterpenoids and amino acids. Synthesis and application for catalysis of addition of diethylzinc to aldehydes