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引用次数: 0
摘要
在钛催化的末端 1,2 二烯同环镁反应的基础上，开发出了一种高产率和高立体选择性合成 1Z,5Z,9Z,13Z-四烯的有效方法。此外，还阐述了一种合成含有 Z 双键取代基的烯烃的新方法。
Ti-catalyzed homocyclomagnesiation of (Z)-1,2,6-trienes in the stereoselective synthesis of 1Z,5Z,9Z,13Z-tetraenes
On the basis of the Ti-catalyzed homocyclomagnesiation of terminal 1,2-dienes, an effective method for the synthesis of 1Z,5Z,9Z,13Z-tetraenes in high yields and high stereoselectivity has been developed. A new approach to the synthesis of allenes with substituents containing Z-double bonds has been elaborated.
期刊介绍：
Publishing nearly 500 original articles a year, by leading Scientists from Russia and throughout the world, Russian Chemical Bulletin is a prominent international journal. The coverage of the journal spans practically all areas of fundamental chemical research and is presented in five sections:
General and Inorganic Chemistry;
Physical Chemistry;
Organic Chemistry;
Organometallic Chemistry;
Chemistry of Natural Compounds and Bioorganic Chemistry.
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