G. N. Kadikova, E. S. Meshcheryakova, L. M. Khalilov
{"title":"2- 丙基环己酮与 N-苯基马来酰亚胺的二烯合成","authors":"G. N. Kadikova, E. S. Meshcheryakova, L. M. Khalilov","doi":"10.1007/s11172-024-4311-x","DOIUrl":null,"url":null,"abstract":"<p>The [4π+2π]-cycloaddition of <i>N</i>-phenylmaleimide to 2-tropylcyclohexanone was performed to prepare previously unknown 9-(2-oxocyclohexyl)-4-phenyl-4-azatetra-cyclo[5.3.2.0<sup>2,6</sup>.0<sup>8,10</sup>]dodec-11-ene-3,5-dione in 92% yield. The structure of the azacyclic compound was established by modern methods, including 1D and 2D NMR spectroscopy and X-ray diffraction analysis.</p>","PeriodicalId":756,"journal":{"name":"Russian Chemical Bulletin","volume":null,"pages":null},"PeriodicalIF":1.7000,"publicationDate":"2024-08-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Diene synthesis of 2-tropylcyclohexanone with N-phenylmaleimide\",\"authors\":\"G. N. Kadikova, E. S. Meshcheryakova, L. M. Khalilov\",\"doi\":\"10.1007/s11172-024-4311-x\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>The [4π+2π]-cycloaddition of <i>N</i>-phenylmaleimide to 2-tropylcyclohexanone was performed to prepare previously unknown 9-(2-oxocyclohexyl)-4-phenyl-4-azatetra-cyclo[5.3.2.0<sup>2,6</sup>.0<sup>8,10</sup>]dodec-11-ene-3,5-dione in 92% yield. The structure of the azacyclic compound was established by modern methods, including 1D and 2D NMR spectroscopy and X-ray diffraction analysis.</p>\",\"PeriodicalId\":756,\"journal\":{\"name\":\"Russian Chemical Bulletin\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":1.7000,\"publicationDate\":\"2024-08-31\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Russian Chemical Bulletin\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://doi.org/10.1007/s11172-024-4311-x\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Russian Chemical Bulletin","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1007/s11172-024-4311-x","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
摘要
通过 N-苯基马来酰亚胺与 2-丙基环己酮的[4π+2π]-环加成反应，制备出了之前未知的 9-(2-氧代环己基)-4-苯基-4-氮杂四环[5.3.2.02,6.08,10]十二-11-烯-3,5-二酮，收率为 92%。该氮杂环化合物的结构是通过现代方法（包括一维和二维核磁共振光谱以及 X 射线衍射分析）确定的。
Diene synthesis of 2-tropylcyclohexanone with N-phenylmaleimide
The [4π+2π]-cycloaddition of N-phenylmaleimide to 2-tropylcyclohexanone was performed to prepare previously unknown 9-(2-oxocyclohexyl)-4-phenyl-4-azatetra-cyclo[5.3.2.02,6.08,10]dodec-11-ene-3,5-dione in 92% yield. The structure of the azacyclic compound was established by modern methods, including 1D and 2D NMR spectroscopy and X-ray diffraction analysis.
期刊介绍：
Publishing nearly 500 original articles a year, by leading Scientists from Russia and throughout the world, Russian Chemical Bulletin is a prominent international journal. The coverage of the journal spans practically all areas of fundamental chemical research and is presented in five sections:
General and Inorganic Chemistry;
Physical Chemistry;
Organic Chemistry;
Organometallic Chemistry;
Chemistry of Natural Compounds and Bioorganic Chemistry.
京公网安备 11010802042870号
京ICP备2023020795号-1
分享
求助内容：
应助结果提醒方式：
扫码关注我们
