合成含有环脂族分子的低聚四亚甲基环氧二胺,作为带有末端环氧基团的化合物的固化剂

IF 1.7 4区 化学 Q3 CHEMISTRY, MULTIDISCIPLINARY Russian Chemical Bulletin Pub Date : 2024-08-31 DOI:10.1007/s11172-024-4323-6
A. I. Slobodinyuk, D. G. Slobodinyuk
{"title":"合成含有环脂族分子的低聚四亚甲基环氧二胺,作为带有末端环氧基团的化合物的固化剂","authors":"A. I. Slobodinyuk,&nbsp;D. G. Slobodinyuk","doi":"10.1007/s11172-024-4323-6","DOIUrl":null,"url":null,"abstract":"<div><p>New oligoether diamines were synthesized via the step of obtaining oligoether diacrylates, followed by their subsequent reaction with 3-aminomethyl-3,5,5-trimethylcyclohexylamine. A series of urethane-containing elastomers based on them was obtained. The polymers were evaluated by differential scanning calorimetry, and their deformation and strength characteristics were also estimated. It was demonstrated that a low glass transition temperature is characteristic of all the polymers.</p></div>","PeriodicalId":756,"journal":{"name":"Russian Chemical Bulletin","volume":"73 7","pages":"2028 - 2033"},"PeriodicalIF":1.7000,"publicationDate":"2024-08-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Synthesis of oligotetramethylene oxide diamines containing cycloaliphatic moieties as the hardeners for compounds with terminal epoxy groups\",\"authors\":\"A. I. Slobodinyuk,&nbsp;D. G. Slobodinyuk\",\"doi\":\"10.1007/s11172-024-4323-6\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>New oligoether diamines were synthesized via the step of obtaining oligoether diacrylates, followed by their subsequent reaction with 3-aminomethyl-3,5,5-trimethylcyclohexylamine. A series of urethane-containing elastomers based on them was obtained. The polymers were evaluated by differential scanning calorimetry, and their deformation and strength characteristics were also estimated. It was demonstrated that a low glass transition temperature is characteristic of all the polymers.</p></div>\",\"PeriodicalId\":756,\"journal\":{\"name\":\"Russian Chemical Bulletin\",\"volume\":\"73 7\",\"pages\":\"2028 - 2033\"},\"PeriodicalIF\":1.7000,\"publicationDate\":\"2024-08-31\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Russian Chemical Bulletin\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s11172-024-4323-6\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Russian Chemical Bulletin","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1007/s11172-024-4323-6","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0

摘要

通过获得低聚醚二丙烯酸酯,然后与 3-aminomethyl-3,5,5-trimethylcyclohexylamine 反应,合成了新的低聚醚二胺。在此基础上获得了一系列含氨基甲酸乙酯的弹性体。通过差示扫描量热法对这些聚合物进行了评估,并估算了它们的变形和强度特性。结果表明,所有聚合物的玻璃化转变温度都很低。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
查看原文
分享 分享
微信好友 朋友圈 QQ好友 复制链接
本刊更多论文
Synthesis of oligotetramethylene oxide diamines containing cycloaliphatic moieties as the hardeners for compounds with terminal epoxy groups

New oligoether diamines were synthesized via the step of obtaining oligoether diacrylates, followed by their subsequent reaction with 3-aminomethyl-3,5,5-trimethylcyclohexylamine. A series of urethane-containing elastomers based on them was obtained. The polymers were evaluated by differential scanning calorimetry, and their deformation and strength characteristics were also estimated. It was demonstrated that a low glass transition temperature is characteristic of all the polymers.

求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
Russian Chemical Bulletin
Russian Chemical Bulletin 化学-化学综合
CiteScore
2.70
自引率
47.10%
发文量
257
审稿时长
3-8 weeks
期刊介绍: Publishing nearly 500 original articles a year, by leading Scientists from Russia and throughout the world, Russian Chemical Bulletin is a prominent international journal. The coverage of the journal spans practically all areas of fundamental chemical research and is presented in five sections: General and Inorganic Chemistry; Physical Chemistry; Organic Chemistry; Organometallic Chemistry; Chemistry of Natural Compounds and Bioorganic Chemistry.
期刊最新文献
Interaction of 2-unsubstituted imidazole N-oxides with electron-deficient olefins: a quantum chemical analysis Determination of intracrystalline diffusion coefficient of organic solvents in metal organic framework adsorbents by zero-length column method Current trends in organic chemistry: contribution of the N. D. Zelinsky Institute of Organic Chemistry of the Russian Academy of Sciences Triphenylphosphine in the identification of oxidation products of organic compounds with molecular oxygen and peroxides In situ spectroelectrochemical and nanomechanical studies in the atomic force microscopy mode of the oxidation—reduction processes of poly-N,N′-ethylenebis(3-methoxysalicylideneimine)
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
已复制链接
已复制链接
快去分享给好友吧!
我知道了
×
扫码分享
扫码分享
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1