Daniel Lozano-Martín, Rodrigo Susial, Pedro Hernández, Teresa E. Fernández-Vicente, M. Carmen Martín, José J. Segovia
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Speed of sound and phase equilibria for ($CO_{2}$ + $C_{3}H_{8}$) mixtures
This work presents phase envelope and speed of sound data for the (0.60
$CO_{2}$ + 0.40 $C_{3}H_{8}$) and (0.80 $CO_{2}$ + 0.20 $C_{3}H_{8}$) binary
mixtures. Phase equilibria was measured using a cylindrical resonator working
in the microwave band whereas an acoustic resonator was used for speed of sound
measurements. The experimental results were compared with GERG-2008 equation of
state, obtaining average absolute deviations by 0.24% in pressure for phase
equilibria data and 0.025% for speed of sound data. Speed of sound values were
used to derive perfect-gas heat capacities, acoustic virial coefficients, and
second density virial coefficients. In addition, AGA8-DC92 equation of state
performance was checked for the results derived from speeds of sound.