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引用次数: 0
摘要
新型铌酸镍[B2O2(OH)4]是在 9 GPa 和 800 °C 的高压/高温条件下合成的。通过单晶 X 射线衍射分析确定了其结构。镍[B2O2(OH)4]的单晶红外光谱证明了 O-H 键的存在。本文讨论了该化合物与总式为 Ca[B2O2(OH)4] 的矿物 vimsite 以及栅硼酸盐 HP-Ni(B2O4) 在结构上的异同。标题化合物可以说是后者的结构水解产物。
High‐Pressure Synthesis and Crystal Structure of the Inoborate Ni[B2O2(OH)4]
The novel inoborate Ni[B2O2(OH)4] was synthesized under high‐pressure/high‐temperature conditions of 9 GPa and 800 °C. Its structure was determined via single‐crystal X‐ray diffraction analysis. The single‐grain IR‐spectrum of Ni[B2O2(OH)4] supports the existence of O–H bonds. The structural similarities and differences with the mineral vimsite possessing the sum formula Ca[B2O2(OH)4], as well as with the phylloborate HP‐Ni(B2O4) is discussed. The title compound can be described as the structural hydrolysis product of the latter.
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