{"title":"Sn5Bi3]3- 的合成与单晶 X 射线表征","authors":"Ute Friedrich, Franz Schmidt, Nikolaus Korber","doi":"10.1002/zaac.202400086","DOIUrl":null,"url":null,"abstract":"The extraction of the solid state materials <jats:italic>“M</jats:italic>SnBi<jats:sub><jats:italic>x</jats:italic></jats:sub><jats:italic>“</jats:italic> (<jats:italic>M</jats:italic>/<jats:italic>x</jats:italic>=Cs/1, Na/3) in liquid ammonia in the presence of different chelating agents yielded the novel Zintl anion [Sn<jats:sub>5</jats:sub>Bi<jats:sub>3</jats:sub>]<jats:sup>3−</jats:sup>. The anion could be crystallized and characterized via single crystal X‐ray diffraction in [Cs@[18]crown‐6]<jats:sub>3</jats:sub>[Sn<jats:sub>5</jats:sub>Bi<jats:sub>3</jats:sub>] ⋅ 7NH<jats:sub>3</jats:sub>, [K@[18]crown‐6]<jats:sub>1.5</jats:sub>[Cs@[18]crown‐6][Cs@([18]crown‐6)<jats:sub>2</jats:sub>]<jats:sub>0.5</jats:sub>[Sn<jats:sub>5</jats:sub>Bi<jats:sub>3</jats:sub>] ⋅ 3.98NH<jats:sub>3</jats:sub>, [Na@DB[18]crown‐6]<jats:sub>2</jats:sub>[Na(NH<jats:sub>3</jats:sub>)<jats:sub>6</jats:sub>][Sn<jats:sub>5</jats:sub>Bi<jats:sub>3</jats:sub>] ⋅ 14NH<jats:sub>3</jats:sub> and [Cs@[2.2.2]crypt]<jats:sub>6</jats:sub>[Sn<jats:sub>5</jats:sub>Bi<jats:sub>3</jats:sub>]<jats:sub>2</jats:sub> ⋅ 9.53NH<jats:sub>3</jats:sub>. The [Sn<jats:sub>5</jats:sub>Bi<jats:sub>3</jats:sub>]<jats:sup>3−</jats:sup> anion is further investigated by mass spectrometry and DFT calculations to confirm its composition and elucidate its electronic structure.","PeriodicalId":23934,"journal":{"name":"Zeitschrift für anorganische und allgemeine Chemie","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"2024-09-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Synthesis and Single Crystal X‐ray Characterization of [Sn5Bi3]3−\",\"authors\":\"Ute Friedrich, Franz Schmidt, Nikolaus Korber\",\"doi\":\"10.1002/zaac.202400086\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The extraction of the solid state materials <jats:italic>“M</jats:italic>SnBi<jats:sub><jats:italic>x</jats:italic></jats:sub><jats:italic>“</jats:italic> (<jats:italic>M</jats:italic>/<jats:italic>x</jats:italic>=Cs/1, Na/3) in liquid ammonia in the presence of different chelating agents yielded the novel Zintl anion [Sn<jats:sub>5</jats:sub>Bi<jats:sub>3</jats:sub>]<jats:sup>3−</jats:sup>. The anion could be crystallized and characterized via single crystal X‐ray diffraction in [Cs@[18]crown‐6]<jats:sub>3</jats:sub>[Sn<jats:sub>5</jats:sub>Bi<jats:sub>3</jats:sub>] ⋅ 7NH<jats:sub>3</jats:sub>, [K@[18]crown‐6]<jats:sub>1.5</jats:sub>[Cs@[18]crown‐6][Cs@([18]crown‐6)<jats:sub>2</jats:sub>]<jats:sub>0.5</jats:sub>[Sn<jats:sub>5</jats:sub>Bi<jats:sub>3</jats:sub>] ⋅ 3.98NH<jats:sub>3</jats:sub>, [Na@DB[18]crown‐6]<jats:sub>2</jats:sub>[Na(NH<jats:sub>3</jats:sub>)<jats:sub>6</jats:sub>][Sn<jats:sub>5</jats:sub>Bi<jats:sub>3</jats:sub>] ⋅ 14NH<jats:sub>3</jats:sub> and [Cs@[2.2.2]crypt]<jats:sub>6</jats:sub>[Sn<jats:sub>5</jats:sub>Bi<jats:sub>3</jats:sub>]<jats:sub>2</jats:sub> ⋅ 9.53NH<jats:sub>3</jats:sub>. The [Sn<jats:sub>5</jats:sub>Bi<jats:sub>3</jats:sub>]<jats:sup>3−</jats:sup> anion is further investigated by mass spectrometry and DFT calculations to confirm its composition and elucidate its electronic structure.\",\"PeriodicalId\":23934,\"journal\":{\"name\":\"Zeitschrift für anorganische und allgemeine Chemie\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2024-09-09\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Zeitschrift für anorganische und allgemeine Chemie\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1002/zaac.202400086\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Zeitschrift für anorganische und allgemeine Chemie","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1002/zaac.202400086","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0
摘要
固态材料 "MSnBix"（M/x=Cs/1，Na/3）在不同螯合剂存在下于液氨中萃取，得到了新型 Zintl 阴离子[Sn5Bi3]3-。该阴离子可以结晶，并通过单晶 X 射线衍射在[Cs@[18]crown-6]3[Sn5Bi3]⋅7NH3、[K@[18]crown-6]1.5[Cs@[18]crown-6][Cs@([18]crown-6)2]0.5[Sn5Bi3]⋅3.98NH3，[Na@DB[18]crown-6]2[Na(NH3)6][Sn5Bi3]⋅14NH3 和 [Cs@[2.2.2]crypt]6[Sn5Bi3]2⋅9.53NH3。质谱法和 DFT 计算进一步研究了[Sn5Bi3]3-阴离子，以确认其组成并阐明其电子结构。
Synthesis and Single Crystal X‐ray Characterization of [Sn5Bi3]3−
The extraction of the solid state materials “MSnBix“ (M/x=Cs/1, Na/3) in liquid ammonia in the presence of different chelating agents yielded the novel Zintl anion [Sn5Bi3]3−. The anion could be crystallized and characterized via single crystal X‐ray diffraction in [Cs@[18]crown‐6]3[Sn5Bi3] ⋅ 7NH3, [K@[18]crown‐6]1.5[Cs@[18]crown‐6][Cs@([18]crown‐6)2]0.5[Sn5Bi3] ⋅ 3.98NH3, [Na@DB[18]crown‐6]2[Na(NH3)6][Sn5Bi3] ⋅ 14NH3 and [Cs@[2.2.2]crypt]6[Sn5Bi3]2 ⋅ 9.53NH3. The [Sn5Bi3]3− anion is further investigated by mass spectrometry and DFT calculations to confirm its composition and elucidate its electronic structure.
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