通过成分调节抑制刚玉-莫来石隔热瓦的热传递

IF 3.5 3区 材料科学 Q1 MATERIALS SCIENCE, CERAMICS Journal of the American Ceramic Society Pub Date : 2024-08-19 DOI:10.1111/jace.20100
Bianlei Hao, Guangchao Sun, Fatang Xu, Lunliang Zhang, Kaiqi Liu
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引用次数: 0

摘要

燃气轮机尺寸和效率的增加导致燃烧室温度升高,对隔热瓦的性能提出了更高的要求。刚玉莫来石具有耐高温、抗热震、导热系数低等特点,一直被广泛使用。然而,如何在确保安全使用高温隔热瓦的同时,通过成分调节抑制热传递,是提高燃气轮机热转换效率的关键。本研究采用浇铸成型法制备隔热瓦。在确定骨料中最佳刚玉/莫来石比例(22:45 wt%)的基础上,通过添加氧化镁(2 wt%)降低了样品的热导率。结果表明,由相组成变化引起的声子本征散射和缺陷散射有效地将隔热瓦样品的导热率降至 2.05 W-m-1-K-1,比调节前的最大值降低了 34.71%。在30个循环的热冲击(1000℃空冷)过程中,残余强度逐渐降低并趋于稳定,最低为8.6 MPa,表明隔热瓦在不影响燃气轮机安全的前提下,可以提供更好的隔热性能,为提高高温隔热材料的隔热性能提供了新的思路和方法。
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Heat transfer inhibition of corundum–mullite insulation tiles through composition regulation

The increase in size and efficiency of gas turbines leads to higher temperature in the combustion chamber, putting greater demands on the performance of the thermal insulation tiles. Corundum–mullite has been used because of its high-temperature resistance, thermal shock resistance, and low thermal conductivity. However, how to inhibit heat transfer through composition regulation while ensuring the safe use of high-temperature insulation tiles is the key to improving the heat conversion efficiency of gas turbines. In this study, thermal insulation tiles were prepared by casting molding. On the basis of determining the optimal corundum/mullite ratio (22:45 wt%) in the aggregate, the thermal conductivity of the sample was reduced by adding MgO (2 wt%). The results show that phonon intrinsic and defect scattering, caused by changes in phase composition, effectively reduce the thermal conductivity of the insulation tile sample to 2.05 W·m−1·K−1, which is 34.71 % lower than the maximum value before regulation. During 30 cycles of thermal shock (air-cooling at 1000°C), the residual strength gradually decreased and tended to be stable, with a minimum of 8.6 MPa, indicating that the thermal insulation tile can provide better thermal insulation without affecting the safety of gas turbines, providing new ideas and methods for improving the thermal insulation performance of high-temperature thermal insulation materials.

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来源期刊
Journal of the American Ceramic Society
Journal of the American Ceramic Society 工程技术-材料科学:硅酸盐
CiteScore
7.50
自引率
7.70%
发文量
590
审稿时长
2.1 months
期刊介绍: The Journal of the American Ceramic Society contains records of original research that provide insight into or describe the science of ceramic and glass materials and composites based on ceramics and glasses. These papers include reports on discovery, characterization, and analysis of new inorganic, non-metallic materials; synthesis methods; phase relationships; processing approaches; microstructure-property relationships; and functionalities. Of great interest are works that support understanding founded on fundamental principles using experimental, theoretical, or computational methods or combinations of those approaches. All the published papers must be of enduring value and relevant to the science of ceramics and glasses or composites based on those materials. Papers on fundamental ceramic and glass science are welcome including those in the following areas: Enabling materials for grand challenges[...] Materials design, selection, synthesis and processing methods[...] Characterization of compositions, structures, defects, and properties along with new methods [...] Mechanisms, Theory, Modeling, and Simulation[...] JACerS accepts submissions of full-length Articles reporting original research, in-depth Feature Articles, Reviews of the state-of-the-art with compelling analysis, and Rapid Communications which are short papers with sufficient novelty or impact to justify swift publication.
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