第 V 章 气体燃烧中活性粒子之间的均相和异相反应

IF 16.4 1区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY Accounts of Chemical Research Pub Date : 2024-08-20 DOI:10.1134/S0023158424601293
V. V. Azatyan
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引用次数: 0

摘要

摘要 解释了火焰中原子和自由基的形成,其浓度比燃烧温度下的平衡值高出许多数量级。研究结果证明了原子和自由基之间的同相和异相反应在燃烧中的重要作用。实验结果说明了以前未知的异质链传播反应在燃烧中的决定性作用。解释了一些试图否认链式燃烧的外国和俄罗斯作者的错误观点的原因。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

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Chapter V. Homogeneous and Heterogeneous Reactions between Active Particles in Gas Combustion

The formation of atoms and radicals in the flame in concentrations by many orders of magnitude higher than the equilibrium values at combustion temperatures is explained. Results that prove the important role of homogeneous and heterogeneous reactions between atoms and radicals in combustion are presented. The decisive role of previously unknown reactions of heterogeneous chain propagation in combustion is illustrated by experimental results. The reasons for the misconceptions of several foreign and Russian authors who tried to deny chain combustion are explained.

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来源期刊
Accounts of Chemical Research
Accounts of Chemical Research 化学-化学综合
CiteScore
31.40
自引率
1.10%
发文量
312
审稿时长
2 months
期刊介绍: Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance. Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.
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