{"title":"利用二氧化碳进行脂肪酶催化反应的介质工程","authors":"Tomoko Matsuda, Hai Nam Hoang","doi":"10.1002/aocs.12895","DOIUrl":null,"url":null,"abstract":"One of the most frequently used biocatalysts for organic synthesis is lipase, a triacylglycerol hydrolase, that also catalyzes esterification in non‐aqueous solvents. Various non‐aqueous solvents such as organic solvents, ionic liquids, and pressurized carbon dioxide (CO<jats:sub>2</jats:sub>) have been employed for lipase‐catalyzed reactions. Notably, pressurized CO<jats:sub>2</jats:sub> (supercritical CO<jats:sub>2</jats:sub>, liquid CO<jats:sub>2</jats:sub>, CO<jats:sub>2</jats:sub>‐expanded liquid) serves as a functional green solvent. This review briefly outlines the properties of pressurized CO<jats:sub>2</jats:sub> relevant to biocatalysis and provides examples of utilizing pressurized CO<jats:sub>2</jats:sub> solvents for efficient synthesis with immobilized lipases.","PeriodicalId":501405,"journal":{"name":"The Journal of the American Oil Chemists’ Society","volume":"57 1","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2024-09-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Medium engineering of lipase‐catalyzed reaction using CO2\",\"authors\":\"Tomoko Matsuda, Hai Nam Hoang\",\"doi\":\"10.1002/aocs.12895\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"One of the most frequently used biocatalysts for organic synthesis is lipase, a triacylglycerol hydrolase, that also catalyzes esterification in non‐aqueous solvents. Various non‐aqueous solvents such as organic solvents, ionic liquids, and pressurized carbon dioxide (CO<jats:sub>2</jats:sub>) have been employed for lipase‐catalyzed reactions. Notably, pressurized CO<jats:sub>2</jats:sub> (supercritical CO<jats:sub>2</jats:sub>, liquid CO<jats:sub>2</jats:sub>, CO<jats:sub>2</jats:sub>‐expanded liquid) serves as a functional green solvent. This review briefly outlines the properties of pressurized CO<jats:sub>2</jats:sub> relevant to biocatalysis and provides examples of utilizing pressurized CO<jats:sub>2</jats:sub> solvents for efficient synthesis with immobilized lipases.\",\"PeriodicalId\":501405,\"journal\":{\"name\":\"The Journal of the American Oil Chemists’ Society\",\"volume\":\"57 1\",\"pages\":\"\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2024-09-04\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"The Journal of the American Oil Chemists’ Society\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1002/aocs.12895\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"The Journal of the American Oil Chemists’ Society","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1002/aocs.12895","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Medium engineering of lipase‐catalyzed reaction using CO2
One of the most frequently used biocatalysts for organic synthesis is lipase, a triacylglycerol hydrolase, that also catalyzes esterification in non‐aqueous solvents. Various non‐aqueous solvents such as organic solvents, ionic liquids, and pressurized carbon dioxide (CO2) have been employed for lipase‐catalyzed reactions. Notably, pressurized CO2 (supercritical CO2, liquid CO2, CO2‐expanded liquid) serves as a functional green solvent. This review briefly outlines the properties of pressurized CO2 relevant to biocatalysis and provides examples of utilizing pressurized CO2 solvents for efficient synthesis with immobilized lipases.
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