{"title":"二茂铁基甲醛的二茂铁基胺醇与氨基醇的合成及其晶体结构","authors":"Dan-Dan Lu, Ya-Meng Zhu, Yi-Jie Li, Ai-Quan Jia, Qian-Feng Zhang","doi":"10.1007/s10870-024-01029-y","DOIUrl":null,"url":null,"abstract":"<div><p>Two chiral ferrocenylamine alcohols of <i>(R)-</i>[Fe(η<sup>5</sup>-C<sub>5</sub>H<sub>5</sub>){η<sup>5</sup>-C<sub>5</sub>H<sub>4</sub>CH<sub>2</sub>NHCH(<sup><i>i</i></sup>Pr)(CH<sub>2</sub>OH)}] (<b>1</b>) and <i>(R)-</i>[Fe(η<sup>5</sup>-C<sub>5</sub>H<sub>5</sub>){η<sup>5</sup>-C<sub>5</sub>H<sub>4</sub>CH<sub>2</sub>NHCH(C<sub>6</sub>H<sub>5</sub>)(CH<sub>2</sub>OH)}] (<b>2</b>) were synthesized by condensation reaction of ferrocenylformaldehyde and chiral aminoalcohols followed by the reduction with sodium borohydride. The crystal structures of the two compounds were determined by single crystal X-ray diffraction. Compound <b>1</b> crystallizes in the orthorhombic space group <i>P</i>2<sub>1</sub>2<sub>1</sub>2 with <i>a</i> = 16.600(8) Å, <i>b</i> = 28.990(14) Å, <i>c</i> = 6.531(3) Å, and <i>Z</i> = 8. Compound 21.13H<sub>2</sub>O crystallizes in the monoclinic space group <i>I</i>2 with <i>a</i> = 22.671(4) Å, <i>b</i> = 6.2481(10) Å, <i>c</i> = 22.112(4) Å, <i>β</i> = 96.763(12)°, and <i>Z</i> = 8.</p><h3>Graphical Abstract</h3><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":615,"journal":{"name":"Journal of Chemical Crystallography","volume":"54 4","pages":"358 - 363"},"PeriodicalIF":0.4000,"publicationDate":"2024-08-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Synthesis and Crystal Structures of Ferrocenylamine Alcohols of Ferrocenylformaldehyde with Aminoalcohols\",\"authors\":\"Dan-Dan Lu, Ya-Meng Zhu, Yi-Jie Li, Ai-Quan Jia, Qian-Feng Zhang\",\"doi\":\"10.1007/s10870-024-01029-y\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Two chiral ferrocenylamine alcohols of <i>(R)-</i>[Fe(η<sup>5</sup>-C<sub>5</sub>H<sub>5</sub>){η<sup>5</sup>-C<sub>5</sub>H<sub>4</sub>CH<sub>2</sub>NHCH(<sup><i>i</i></sup>Pr)(CH<sub>2</sub>OH)}] (<b>1</b>) and <i>(R)-</i>[Fe(η<sup>5</sup>-C<sub>5</sub>H<sub>5</sub>){η<sup>5</sup>-C<sub>5</sub>H<sub>4</sub>CH<sub>2</sub>NHCH(C<sub>6</sub>H<sub>5</sub>)(CH<sub>2</sub>OH)}] (<b>2</b>) were synthesized by condensation reaction of ferrocenylformaldehyde and chiral aminoalcohols followed by the reduction with sodium borohydride. The crystal structures of the two compounds were determined by single crystal X-ray diffraction. Compound <b>1</b> crystallizes in the orthorhombic space group <i>P</i>2<sub>1</sub>2<sub>1</sub>2 with <i>a</i> = 16.600(8) Å, <i>b</i> = 28.990(14) Å, <i>c</i> = 6.531(3) Å, and <i>Z</i> = 8. Compound 21.13H<sub>2</sub>O crystallizes in the monoclinic space group <i>I</i>2 with <i>a</i> = 22.671(4) Å, <i>b</i> = 6.2481(10) Å, <i>c</i> = 22.112(4) Å, <i>β</i> = 96.763(12)°, and <i>Z</i> = 8.</p><h3>Graphical Abstract</h3><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>\",\"PeriodicalId\":615,\"journal\":{\"name\":\"Journal of Chemical Crystallography\",\"volume\":\"54 4\",\"pages\":\"358 - 363\"},\"PeriodicalIF\":0.4000,\"publicationDate\":\"2024-08-30\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Chemical Crystallography\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s10870-024-01029-y\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"CRYSTALLOGRAPHY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Chemical Crystallography","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1007/s10870-024-01029-y","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CRYSTALLOGRAPHY","Score":null,"Total":0}
Synthesis and Crystal Structures of Ferrocenylamine Alcohols of Ferrocenylformaldehyde with Aminoalcohols
Two chiral ferrocenylamine alcohols of (R)-[Fe(η5-C5H5){η5-C5H4CH2NHCH(iPr)(CH2OH)}] (1) and (R)-[Fe(η5-C5H5){η5-C5H4CH2NHCH(C6H5)(CH2OH)}] (2) were synthesized by condensation reaction of ferrocenylformaldehyde and chiral aminoalcohols followed by the reduction with sodium borohydride. The crystal structures of the two compounds were determined by single crystal X-ray diffraction. Compound 1 crystallizes in the orthorhombic space group P21212 with a = 16.600(8) Å, b = 28.990(14) Å, c = 6.531(3) Å, and Z = 8. Compound 21.13H2O crystallizes in the monoclinic space group I2 with a = 22.671(4) Å, b = 6.2481(10) Å, c = 22.112(4) Å, β = 96.763(12)°, and Z = 8.
期刊介绍：
Journal of Chemical Crystallography is an international and interdisciplinary publication dedicated to the rapid dissemination of research results in the general areas of crystallography and spectroscopy. Timely research reports detail topics in crystal chemistry and physics and their relation to problems of molecular structure; structural studies of solids, liquids, gases, and solutions involving spectroscopic, spectrometric, X-ray, and electron and neutron diffraction; and theoretical studies.
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