宽温度范围环境下 21 700 块圆柱形三元锂电池的热电耦合模型构建

IF 3 3区 工程技术 Q2 CHEMISTRY, ANALYTICAL Journal of Thermal Analysis and Calorimetry Pub Date : 2024-09-05 DOI:10.1007/s10973-024-13560-3
Haopeng Chen, Tianshi Zhang, Haibo Chen, Qing Gao
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引用次数: 0

摘要

锂离子电池的电化学特性、发热特性和安全性受环境温度的影响很大。本文以 21700 块圆柱形三元锂电池为例,采用实验与仿真相结合的方法,揭示了电池热电耦合特性在宽温度范围环境(- 20 ℃ 至 40 ℃)下的差异。我们设计了电池模型表征方法,开展了不同环境温度下电池充放电特性实验,提取了各自的建模关键参数,揭示了不同温度下的参数差异,构建了宽温区环境下的电池热电耦合模型。同时,我们利用上述构建的模型对电池的热性能进行仿真和实验验证。通过比较红外热成像和 K 型热电偶获得的实验数据与模拟结果,我们发现误差低于 5%。与均匀热源模型不同,本文构建的模型可以模拟不均匀温度场。与等效电路模型和电化学-热耦合模型相比,它涉及的计算量更少。它既考虑了模拟电池热性能的精度,又考虑了面向市场普及的实用性,为宽温度范围环境下电池热管理设计的相关研究和面向市场普及奠定了基础。
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Thermoelectric coupling model construction of 21,700 cylindrical ternary lithium batteries under wide temperature range environment

The electrochemical properties, heat production properties and safety of lithium-ion batteries are significantly affected by the ambient temperature. In this paper, a combination of experimental and simulation methods is used to reveal the differences of the battery thermoelectric coupling characteristics under wide temperature range environment (from − 20 ℃ to 40 ℃) by taking 21,700 cylindrical ternary lithium batteries as examples. We design the battery model characterization method, carry out the battery charging and discharging characteristics experiments under different ambient temperatures, extract the respective modeling key parameters, reveal the differences of parameters under different temperatures, and construct the battery thermoelectric coupling model under wide temperature range environment. Simultaneously, we utilize the model constructed above to conduct simulations and experimentally verify battery thermal performance. By comparing experimental data acquired through infrared thermography and K-type thermocouples with simulation outcomes, we find the error to be below 5%. Unlike the homogeneous heat source model, the model constructed in this paper can simulate the uneven temperature field. In comparison to both equivalent circuit models and electrochemical-thermal coupling models, it involves fewer computations. It considers both the precision of simulating battery thermal performance and practicality for market-oriented popularity, which lays the foundation for research and market-oriented popularity related to battery thermal management design under wide temperature range environment.

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来源期刊
CiteScore
8.50
自引率
9.10%
发文量
577
审稿时长
3.8 months
期刊介绍: Journal of Thermal Analysis and Calorimetry is a fully peer reviewed journal publishing high quality papers covering all aspects of thermal analysis, calorimetry, and experimental thermodynamics. The journal publishes regular and special issues in twelve issues every year. The following types of papers are published: Original Research Papers, Short Communications, Reviews, Modern Instruments, Events and Book reviews. The subjects covered are: thermogravimetry, derivative thermogravimetry, differential thermal analysis, thermodilatometry, differential scanning calorimetry of all types, non-scanning calorimetry of all types, thermometry, evolved gas analysis, thermomechanical analysis, emanation thermal analysis, thermal conductivity, multiple techniques, and miscellaneous thermal methods (including the combination of the thermal method with various instrumental techniques), theory and instrumentation for thermal analysis and calorimetry.
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