传统陶瓷工业中黑色颜料 CAS 玻璃的用途:生产、金属化障碍以及陶瓷工艺色彩评估的新方法

IF 1.3 4区 材料科学 Q3 CHEMISTRY, APPLIED Pigment & Resin Technology Pub Date : 2024-09-12 DOI:10.1108/prt-02-2024-0018
Nandalal Acharjee, Subhas Ganguly, Prasenjit Biswas, Bidyapati Sarangi
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引用次数: 0

摘要

本研究的目的是开发黑色颜料陶瓷炻器坯体,将材料成分和色彩潜力的各个方面融为一体。最近的研究探索了黑色颜料铝硅酸钙玻璃 (BPCG),这是一种以其独特性能而著称的特殊材料,有望改变传统陶瓷的着色能力。设计/方法/方法在这项研究中,首先通过研磨工艺制备了复合陶瓷样品 (B-1),然后进行筛分分析,以达到 44 微米以内的粒度。通过能量色散 X 射线光谱分析、扫描电子显微镜和热重分析,研究了微观分析、形态学和热成像,发现样品-B-1 在 950°C、1050°C、1000°C 和 1180°C 等不同温度下具有良好的烧成收缩率、孔隙率、体积密度和烧成强度以及良好的热塑特性。此外,还以 B-1 为基体合成了 BPCG 辅助颜料陶瓷复合材料。在 5-20 分钟的选择性浸泡范围内,对所合成的复合材料(C 系列)进行了 CIE 实验室调查,调查发现,通过 X 射线衍射研究获得的含有二钴硅化物(26%)、镍铬酸盐、Stilpnomelane(富含铁)等相的 C-10 出现了突出的黑色色调(L:24.09,a*:-0.17,b*:-0.49)。 研究结果陶瓷材料在艺术、工艺和技术领域都发挥着重要作用。艺术领域揭示了概念或装饰,而工艺领域则体现了传统和功能的魅力。原创性/价值 这个 C-10 样品中莫来石的比例较低,这表明 BPCG 均匀地混合在基底(B-1)的基质中,并呈现为海绵状。因此,BPCG 是陶瓷金属化的潜在候选材料,而这种传统的金属化工艺在陶瓷复合材料领域的实践中经常面临一些挑战,如均匀性和混合性。这项研究旨在为艺术装饰开辟新的途径,在传统工艺和现代技术之间架起一座桥梁。此外,BPCG 通过震撼技术在色彩评估中的作用也为陶瓷从业人员、设计师或陶瓷教育工作者增添了一个令人兴奋的概念。
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Uses of black pigmented CAS glass in conventional ceramic industry: production, impediments to metallization, and startling approaches for color evaluation in ceramic tech-artistry

Purpose

The purpose of this study is to develop black pigmented ceramic stoneware bodies that integrate various aspects of material composition and color potential. Recent research has explored black pigmented calcium aluminosilicate glass (BPCG), a specialized material known for its unique properties, which holds promise for transforming the color capabilities of traditional ceramics.

Design/methodology/approach

In this investigation, initially composite ceramic sample (B-1) was prepared by milling process prior to sieve analysis to attain the particle size within 44 microns. Microanalysis and morphology and thermography were studied by energy-dispersive X-ray spectroscopy, scanning electron microscope and thermogravimetric analysis and found Sample-B-1 received attractive properties like firing shrinkage, porosity, bulk density and firing strength along with good pyro-plastic properties at various temperatures like 950°C, 1050°C, 1000°C and 1180°C. Furthermore, BPCG-assisted pigmented ceramic composites were synthesized with B-1 matrix. CIE lab investigation of the attributed composites (C-series) within selective soaking range of 5–20 min was performed, and the investigation found that prominent black hue appeared (L: 24.09, a*: −0.17, b*: −0.49) for C-10 containing appeared phases of Di-Co-Silicide (26%), Ni-Chromite, Stilpnomelane (rich in iron) as obtained by X-ray diffraction studies.

Findings

Ceramic material played a significant role in the realms of art and craft, as well as in technology. The artistic facet reveals concepts or ornamentation, while the craft echoes both traditional and functional appeal. Technology, on the other hand, involves the logical implementation behind the creation.

Originality/value

This C-10 Sample comprised the lower percentage of mullite which attributed that the BPCG homogeneously mixed in the matrix of base (B-1) and appeared as spinal staff. Therefore, BPCG was a potential candidate for ceramic metallization, and this traditional metallization processes often faced some challenges like uniformity and mixing in the ceramic composite domain practices. This study aimed to open up new avenues for artistic decoration and bridging the gap between traditional craftsmanship and modern technology. Furthermore, BPCG’s role in color assessment through shocking techniques added an exciting concept for the ceramic practitioners, designers or ceramic educators.

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来源期刊
Pigment & Resin Technology
Pigment & Resin Technology 工程技术-材料科学:膜
CiteScore
2.80
自引率
21.40%
发文量
91
审稿时长
>12 weeks
期刊介绍: The journal looks at developments in: ■Adhesives and sealants ■Curing and coatings ■Wood coatings and preservatives ■Environmentally compliant coating systems and pigments ■Inks for food packaging ■Manufacturing machinery - reactors, mills mixing and dispersing equipment, pumps ■Packaging, labeling and storage ■Plus topical features and news on materials, coatings, industry people, conferences, books and so on ■Raw materials such as pigments, solvents, resins and chemicals ■Testing equipment and procedures
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