斯堪的纳维亚喀里多尼亚Lykling蛇绿混杂金矿床的成矿模式:流体包裹体、矿物化学和稳定同位素地球化学的启示

IF 3.2 2区 地球科学 Q1 GEOLOGY Ore Geology Reviews Pub Date : 2024-09-10 DOI:10.1016/j.oregeorev.2024.106227
Sabina Strmić Palinkaš , Frida Riple Forsberg , Rolf Birger Pedersen , Håvard Hallås Stubseid , Seán H. McClenaghan , Jorge E. Spangenberg
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引用次数: 0

摘要

Lykling金矿床是斯堪的纳维亚喀里多尼亚上阿尔罗赫通金矿化的一个独特实例。该矿床由早奥陶世的Lykling蛇绿岩复合体和侵入的trondhjemite单元所承载,在空间上与横切蛇绿岩复合体和trondhjemite的两代黑云岩堤相关联。实地观察表明,岩浆岩堤并没有在 Lykling 金矿的成矿过程中发挥积极作用,但它们与直接的母岩(即辉长岩和闪长岩)之间的接触却很重要、Lykling地区热液系统演化的三个主要阶段由两代含金矿石的石英矿脉记录下来:1)由角度适中的脆性-韧性剪切带承载的较古老的石英-碳酸盐矿脉;2)填充于陡倾脆性断层的较年轻的石英-硫化物矿脉。第一阶段是在温度介于 310 ∼ 330 °C、压力介于 2.7 至 3.5 千巴之间的中度含盐 NaCl-CaCl2-H2O ± CO2 流体中沉积贫瘠的石英和不含金的黄铁矿。在特定的物理化学条件下,金以其氯化物络合物的形式流动。第二阶段与多次韧性变形有关,同时伴有角砾岩化,反映了脆-韧性转变过程。流体包裹体数据显示,温度和压力的降低可能导致形成稳定的金-二硫化物复合物,并使金的热液流动性对压力变化敏感。因此,由脆性-韧性结构的发展所控制的压力波动很可能导致石英脉中原生金的沉淀。第三阶段是纯粹的脆性事件,伴随着 fCO2/fS2 比率的显著下降。高温和中盐度流体与低温流体的混合被认为是导致硫化物沉积的主要原因,也是Lykling热液系统中原生金的晚期阶段。Lykling蛇绿混杂金矿床与其他地方的造山型金矿床有许多相似之处,包括成矿过程中的构造控制、中低盐度含二氧化碳水溶液的沉积、沿脆韧性混合断层带的集中流体沉积以及与区域变质地层的空间关联。与绝大多数已知的造山型金矿床不同,Lykling蛇绿混杂金矿床记录的挥发物来源于岩浆。因此,考虑到实地关系和 Lykling 矿床的区域环境,我们认为该矿床的形成与 Sunnhordland Batholith 在碰撞后地壳变薄和 Lykling 蛇绿岩复合体内相关的局部隆起过程中的置换同时发生。
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Metallogenic model of the Lykling ophiolite-hosted lode Au deposit, Scandinavian Caledonides: Insight from fluid inclusions, mineral chemistry and stable isotope geochemistry

The Lykling lode Au deposit represents a unique example of gold mineralization in the Upper Allochthone of the Scandinavian Caledonides. The mineralization is hosted by the Early Ordovician Lykling Ophiolite Complex and the intruding trondhjemite unit and spatially associated with two generations of mafic dykes that crosscut both the ophiolitic complex and trondhjemite. Field observations indicate that the mafic dykes did not play an active role in the emplacement of Au at Lykling, however their contacts with the immediate host rocks (i.e., gabbro and trondhjemite) may have focused ore-forming fluids.

Three main stages in the evolution of the hydrothermal system in the Lykling area are documented by two generations of auriferous quartz veins: 1) older quartz-carbonate veins hosted by moderately angled brittle-ductile shear zones and 2) younger quartz-sulfide veins that fill steeply dipping brittle faults. Stage 1 resulted in deposition of barren quartz and gold-free pyrite from moderately saline NaCl-CaCl2-H2O ± CO2 fluids at temperatures between ∼310–330 °C and pressures in the range from 2.7 to 3.5 kbars. Under the given physicochemical conditions Au was mobile in the form of its chloride complexes. Stage 2 is associated with multiple episodes of ductile deformation punctuated by concomitant brecciation reflecting brittle-ductile transition processes. Fluid inclusion data reveals a decrease in temperature and pressure that may result in the formation of stable Au-bisulfide complexes and making the hydrothermal mobility of Au sensitive to changes in pressure. Consequently, the fluctuation in pressure controlled by the development of brittle-ductile structures likely resulted in the precipitation of native gold in quartz veins. Stage 3 represents a pure brittle event which is accompanied by a significant decrease in the fCO2/fS2 ratio. Mixing of higher-temperature and moderate-salinity fluids with cooler fluids has been recognized as the principal trigger for deposition of sulfides and a paragenetically late phase of native gold in the Lykling hydrothermal system.

The Lykling ophiolite-hosted lode Au deposit shows numerous similarities with orogenic gold deposits elsewhere, including structural controls during mineralizing events, deposition from moderately to low salinity CO2-bearing aqueous solutions, deposition from a focused fluid flow along trans-crustal fault zones with a mixed brittle-ductile character and the spatial association with regionally metamorphosed terranes. In contrast to the great majority of the known orogenic gold deposits, the Lykling ophiolite-hosted lode Au deposit records a magmatic origin of volatiles. Therefore, taking into consideration field relationships and the regional setting of the Lykling deposit, we argue that its formation is concomitant with emplacement of the Sunnhordland Batholith during post-collisional thinning of the crust and associated localized uplift within the Lykling Ophiolite Complex.

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来源期刊
Ore Geology Reviews
Ore Geology Reviews 地学-地质学
CiteScore
6.50
自引率
27.30%
发文量
546
审稿时长
22.9 weeks
期刊介绍: Ore Geology Reviews aims to familiarize all earth scientists with recent advances in a number of interconnected disciplines related to the study of, and search for, ore deposits. The reviews range from brief to longer contributions, but the journal preferentially publishes manuscripts that fill the niche between the commonly shorter journal articles and the comprehensive book coverages, and thus has a special appeal to many authors and readers.
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