{"title":"具有强可回收附着力的机械坚固、热稳定性和自愈合聚酰亚胺网络的软硬结构。","authors":"Zichen Jia, Haiyue Wang, Ping Yu, Hongfei He, Qirui Huang, Wei Hong, Cai Liu, Yanji Shi, Jue Wang, Yumeng Xin, Xuemeng Jia, Juanjuan Ma, Bin Yu","doi":"10.1002/smll.202406821","DOIUrl":null,"url":null,"abstract":"<p><p>Reversible and recyclable thermosets have garnered increasing attention for their smart functionality and sustainability. However, they still face challenges in balancing comprehensive performance and dynamic features. Herein, silicon (Si)─oxygen (O) and imidazole units covalent bonds are coupled to generate a new class of bio-polyimines (Bio-Si-PABZs), to endow them with high performance and excellent reprocessing capability and acid-degradability. By tailoring the molar content of diamines, this Bio-Si-PABZs displayed both a markedly high glass transition temperature (162 °C) and a high char yield at 800 °C in an oxygen atmosphere (73.1%). These Bio-Si-PABZs with their favorable properties outperformed various previously reported polyimines and competed effectively with commercial fossil-based polycarbonate. Moreover, the scratch (≈10 µm) on the surface of samples can be self-healing within only 2 min, and an effective \"Bird Nest\"-to-\"Torch\" recycling can also be achieved through free amines solution. Most importantly, a bio-based siloxane adhesive derived from the intermediate Bio-Si-PABZ-1 by acidic degradation demonstrated broad and robust adhesion in various substrates, with values reaching up to ≈3.5 MPa. For the first time, this study lays the scientific groundwork for designing robust and recyclable polyimine thermosets with Si─O and imidazole units, as well as converting plastic wastes into thermal-reversibility and renewable adhesives.</p>","PeriodicalId":228,"journal":{"name":"Small","volume":null,"pages":null},"PeriodicalIF":13.0000,"publicationDate":"2024-10-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Soft-Rigid Construction of Mechanically Robust, Thermally Stable, and Self-Healing Polyimine Networks with Strongly Recyclable Adhesion.\",\"authors\":\"Zichen Jia, Haiyue Wang, Ping Yu, Hongfei He, Qirui Huang, Wei Hong, Cai Liu, Yanji Shi, Jue Wang, Yumeng Xin, Xuemeng Jia, Juanjuan Ma, Bin Yu\",\"doi\":\"10.1002/smll.202406821\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p><p>Reversible and recyclable thermosets have garnered increasing attention for their smart functionality and sustainability. However, they still face challenges in balancing comprehensive performance and dynamic features. Herein, silicon (Si)─oxygen (O) and imidazole units covalent bonds are coupled to generate a new class of bio-polyimines (Bio-Si-PABZs), to endow them with high performance and excellent reprocessing capability and acid-degradability. By tailoring the molar content of diamines, this Bio-Si-PABZs displayed both a markedly high glass transition temperature (162 °C) and a high char yield at 800 °C in an oxygen atmosphere (73.1%). These Bio-Si-PABZs with their favorable properties outperformed various previously reported polyimines and competed effectively with commercial fossil-based polycarbonate. Moreover, the scratch (≈10 µm) on the surface of samples can be self-healing within only 2 min, and an effective \\\"Bird Nest\\\"-to-\\\"Torch\\\" recycling can also be achieved through free amines solution. Most importantly, a bio-based siloxane adhesive derived from the intermediate Bio-Si-PABZ-1 by acidic degradation demonstrated broad and robust adhesion in various substrates, with values reaching up to ≈3.5 MPa. For the first time, this study lays the scientific groundwork for designing robust and recyclable polyimine thermosets with Si─O and imidazole units, as well as converting plastic wastes into thermal-reversibility and renewable adhesives.</p>\",\"PeriodicalId\":228,\"journal\":{\"name\":\"Small\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":13.0000,\"publicationDate\":\"2024-10-11\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Small\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://doi.org/10.1002/smll.202406821\",\"RegionNum\":2,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Small","FirstCategoryId":"88","ListUrlMain":"https://doi.org/10.1002/smll.202406821","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Soft-Rigid Construction of Mechanically Robust, Thermally Stable, and Self-Healing Polyimine Networks with Strongly Recyclable Adhesion.
Reversible and recyclable thermosets have garnered increasing attention for their smart functionality and sustainability. However, they still face challenges in balancing comprehensive performance and dynamic features. Herein, silicon (Si)─oxygen (O) and imidazole units covalent bonds are coupled to generate a new class of bio-polyimines (Bio-Si-PABZs), to endow them with high performance and excellent reprocessing capability and acid-degradability. By tailoring the molar content of diamines, this Bio-Si-PABZs displayed both a markedly high glass transition temperature (162 °C) and a high char yield at 800 °C in an oxygen atmosphere (73.1%). These Bio-Si-PABZs with their favorable properties outperformed various previously reported polyimines and competed effectively with commercial fossil-based polycarbonate. Moreover, the scratch (≈10 µm) on the surface of samples can be self-healing within only 2 min, and an effective "Bird Nest"-to-"Torch" recycling can also be achieved through free amines solution. Most importantly, a bio-based siloxane adhesive derived from the intermediate Bio-Si-PABZ-1 by acidic degradation demonstrated broad and robust adhesion in various substrates, with values reaching up to ≈3.5 MPa. For the first time, this study lays the scientific groundwork for designing robust and recyclable polyimine thermosets with Si─O and imidazole units, as well as converting plastic wastes into thermal-reversibility and renewable adhesives.
期刊介绍:
Small serves as an exceptional platform for both experimental and theoretical studies in fundamental and applied interdisciplinary research at the nano- and microscale. The journal offers a compelling mix of peer-reviewed Research Articles, Reviews, Perspectives, and Comments.
With a remarkable 2022 Journal Impact Factor of 13.3 (Journal Citation Reports from Clarivate Analytics, 2023), Small remains among the top multidisciplinary journals, covering a wide range of topics at the interface of materials science, chemistry, physics, engineering, medicine, and biology.
Small's readership includes biochemists, biologists, biomedical scientists, chemists, engineers, information technologists, materials scientists, physicists, and theoreticians alike.