{"title":"H2SO4-HNO3 系统在合成金刚烷甲酸中的新特点","authors":"E. A. Ivleva, D. V. Zvereva, Yu. N. Klimochkin","doi":"10.1134/S1070363224080024","DOIUrl":null,"url":null,"abstract":"<p>New methods for the direct preparation of 3-hydroxy-1-adamantanecarboxylic acid and 1,3-adamantanedicarboxylic acid from 1-adamantyl halides was developed. The one-pot methods are based on the sequential combination of the Koch–Haaf and oxidation reactions in a H<sub>2</sub>SO<sub>4</sub>–HNO<sub>3</sub> mixture. This study proposes an improved method for the preparation of 1-adamantanecarboxylic acids from 1-adamantyl halides.</p>","PeriodicalId":761,"journal":{"name":"Russian Journal of General Chemistry","volume":"94 8","pages":"1905 - 1911"},"PeriodicalIF":0.9000,"publicationDate":"2024-10-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"New Features of the H2SO4–HNO3 System in the Synthesis of Adamantanecarboxylic Acids\",\"authors\":\"E. A. Ivleva, D. V. Zvereva, Yu. N. Klimochkin\",\"doi\":\"10.1134/S1070363224080024\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>New methods for the direct preparation of 3-hydroxy-1-adamantanecarboxylic acid and 1,3-adamantanedicarboxylic acid from 1-adamantyl halides was developed. The one-pot methods are based on the sequential combination of the Koch–Haaf and oxidation reactions in a H<sub>2</sub>SO<sub>4</sub>–HNO<sub>3</sub> mixture. This study proposes an improved method for the preparation of 1-adamantanecarboxylic acids from 1-adamantyl halides.</p>\",\"PeriodicalId\":761,\"journal\":{\"name\":\"Russian Journal of General Chemistry\",\"volume\":\"94 8\",\"pages\":\"1905 - 1911\"},\"PeriodicalIF\":0.9000,\"publicationDate\":\"2024-10-04\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Russian Journal of General Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://link.springer.com/article/10.1134/S1070363224080024\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Russian Journal of General Chemistry","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1134/S1070363224080024","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
New Features of the H2SO4–HNO3 System in the Synthesis of Adamantanecarboxylic Acids
New methods for the direct preparation of 3-hydroxy-1-adamantanecarboxylic acid and 1,3-adamantanedicarboxylic acid from 1-adamantyl halides was developed. The one-pot methods are based on the sequential combination of the Koch–Haaf and oxidation reactions in a H2SO4–HNO3 mixture. This study proposes an improved method for the preparation of 1-adamantanecarboxylic acids from 1-adamantyl halides.
期刊介绍：
Russian Journal of General Chemistry is a journal that covers many problems that are of general interest to the whole community of chemists. The journal is the successor to Russia’s first chemical journal, Zhurnal Russkogo Khimicheskogo Obshchestva (Journal of the Russian Chemical Society ) founded in 1869 to cover all aspects of chemistry. Now the journal is focused on the interdisciplinary areas of chemistry (organometallics, organometalloids, organoinorganic complexes, mechanochemistry, nanochemistry, etc.), new achievements and long-term results in the field. The journal publishes reviews, current scientific papers, letters to the editor, and discussion papers.
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