{"title":"用于光纤激光应用的 Er3+/Tm3+ 共掺 CaF2 氧氟硼硅酸盐玻璃陶瓷","authors":"Bungala Chinna Jamalaiah","doi":"10.1016/j.infrared.2024.105571","DOIUrl":null,"url":null,"abstract":"<div><div>Transparent Er<sup>3+</sup>/Tm<sup>3+</sup> codoped CaF<sub>2</sub> based oxyfluoroborosilicate glass-ceramics (BSEr1Tm<em>x</em>GCs) with variable Tm<sup>3+</sup> concentration were prepared through melt quench process followed by reheat treatment at 450 °C/1h. They were characterized through differential scanning calorimetry (DSC), powder X-ray diffraction (XRD), Fourier transform infrared (FTIR) Raman spectroscopy, near infrared (NIR) emission and luminescence decay. The formation of CaF<sub>2</sub> nanocrystallites against oxyfluoroborosilicate glassy phase was confirmed by scanning electron microscopic (SEM) and hi-resolution transmission electron microscopic (HRTEM) studies. The NIR emission properties were investigated at 460 nm diode laser pumping. The applicability of BSEr1Tm<em>x</em>GCs were examined by evaluating effective bandwidth (Δλ<sub>eff</sub>), stimulated emission cross-section (σ<sub>e</sub>), gain bandwidth (σ<sub>e</sub> × Δλ<sub>eff</sub>), figure of merit (σ<sub>e</sub> × τ<sub>R</sub>) and quantum efficiency (η<sub>QE</sub>). The energy transfer efficiency (η<sub>ET</sub>), rate of energy transfer (W<sub>ET</sub>) between Er<sup>3+</sup> and Tm<sup>3+</sup> and the rate of non-radiative transitions (W<sub>NR</sub>) were also calculated. The comparative NIR emission performance suggests that the BSEr1Tm1GC has proficiency for 1530 nm broadband fiber lasers and optical amplifiers in short wavelength and conventional wavelength (S + C) band communication window.</div></div>","PeriodicalId":13549,"journal":{"name":"Infrared Physics & Technology","volume":null,"pages":null},"PeriodicalIF":3.1000,"publicationDate":"2024-10-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Er3+/Tm3+ codoped CaF2 based oxyfluoroborosilicate glass-ceramics for fiber laser applications\",\"authors\":\"Bungala Chinna Jamalaiah\",\"doi\":\"10.1016/j.infrared.2024.105571\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>Transparent Er<sup>3+</sup>/Tm<sup>3+</sup> codoped CaF<sub>2</sub> based oxyfluoroborosilicate glass-ceramics (BSEr1Tm<em>x</em>GCs) with variable Tm<sup>3+</sup> concentration were prepared through melt quench process followed by reheat treatment at 450 °C/1h. They were characterized through differential scanning calorimetry (DSC), powder X-ray diffraction (XRD), Fourier transform infrared (FTIR) Raman spectroscopy, near infrared (NIR) emission and luminescence decay. The formation of CaF<sub>2</sub> nanocrystallites against oxyfluoroborosilicate glassy phase was confirmed by scanning electron microscopic (SEM) and hi-resolution transmission electron microscopic (HRTEM) studies. The NIR emission properties were investigated at 460 nm diode laser pumping. The applicability of BSEr1Tm<em>x</em>GCs were examined by evaluating effective bandwidth (Δλ<sub>eff</sub>), stimulated emission cross-section (σ<sub>e</sub>), gain bandwidth (σ<sub>e</sub> × Δλ<sub>eff</sub>), figure of merit (σ<sub>e</sub> × τ<sub>R</sub>) and quantum efficiency (η<sub>QE</sub>). The energy transfer efficiency (η<sub>ET</sub>), rate of energy transfer (W<sub>ET</sub>) between Er<sup>3+</sup> and Tm<sup>3+</sup> and the rate of non-radiative transitions (W<sub>NR</sub>) were also calculated. The comparative NIR emission performance suggests that the BSEr1Tm1GC has proficiency for 1530 nm broadband fiber lasers and optical amplifiers in short wavelength and conventional wavelength (S + C) band communication window.</div></div>\",\"PeriodicalId\":13549,\"journal\":{\"name\":\"Infrared Physics & Technology\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":3.1000,\"publicationDate\":\"2024-10-05\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Infrared Physics & Technology\",\"FirstCategoryId\":\"101\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S1350449524004559\",\"RegionNum\":3,\"RegionCategory\":\"物理与天体物理\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"INSTRUMENTS & INSTRUMENTATION\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Infrared Physics & Technology","FirstCategoryId":"101","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S1350449524004559","RegionNum":3,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"INSTRUMENTS & INSTRUMENTATION","Score":null,"Total":0}
Er3+/Tm3+ codoped CaF2 based oxyfluoroborosilicate glass-ceramics for fiber laser applications
Transparent Er3+/Tm3+ codoped CaF2 based oxyfluoroborosilicate glass-ceramics (BSEr1TmxGCs) with variable Tm3+ concentration were prepared through melt quench process followed by reheat treatment at 450 °C/1h. They were characterized through differential scanning calorimetry (DSC), powder X-ray diffraction (XRD), Fourier transform infrared (FTIR) Raman spectroscopy, near infrared (NIR) emission and luminescence decay. The formation of CaF2 nanocrystallites against oxyfluoroborosilicate glassy phase was confirmed by scanning electron microscopic (SEM) and hi-resolution transmission electron microscopic (HRTEM) studies. The NIR emission properties were investigated at 460 nm diode laser pumping. The applicability of BSEr1TmxGCs were examined by evaluating effective bandwidth (Δλeff), stimulated emission cross-section (σe), gain bandwidth (σe × Δλeff), figure of merit (σe × τR) and quantum efficiency (ηQE). The energy transfer efficiency (ηET), rate of energy transfer (WET) between Er3+ and Tm3+ and the rate of non-radiative transitions (WNR) were also calculated. The comparative NIR emission performance suggests that the BSEr1Tm1GC has proficiency for 1530 nm broadband fiber lasers and optical amplifiers in short wavelength and conventional wavelength (S + C) band communication window.
期刊介绍：
The Journal covers the entire field of infrared physics and technology: theory, experiment, application, devices and instrumentation. Infrared'' is defined as covering the near, mid and far infrared (terahertz) regions from 0.75um (750nm) to 1mm (300GHz.) Submissions in the 300GHz to 100GHz region may be accepted at the editors discretion if their content is relevant to shorter wavelengths. Submissions must be primarily concerned with and directly relevant to this spectral region.
Its core topics can be summarized as the generation, propagation and detection, of infrared radiation; the associated optics, materials and devices; and its use in all fields of science, industry, engineering and medicine.
Infrared techniques occur in many different fields, notably spectroscopy and interferometry; material characterization and processing; atmospheric physics, astronomy and space research. Scientific aspects include lasers, quantum optics, quantum electronics, image processing and semiconductor physics. Some important applications are medical diagnostics and treatment, industrial inspection and environmental monitoring.
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