一种配体，两种作用：利用三维配体和不对称无机节点构建的新型柱层金属有机框架

IF 3.5 3区化学 Q2 CHEMISTRY, INORGANIC & NUCLEAR Dalton Transactions Pub Date : 2024-10-14 DOI:10.1039/D4DT02061H

Chaozhuang Xue, Yingying Zhang, Kai Zhu, Suyun Deng, Konggang Qu, Shuwen Gong and Huajun Yang

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引用次数: 0

摘要

我们在此展示了两种仅由一种三维（3D）二元配体构建的柱层 MOF。这两种结构中的配体不仅是层内的连接体，还是相邻层之间的 "支柱"。连接体的这种多功能性伴随着不常见的不对称 10-c 金属六聚体或 7-c 四聚体节点，这在以前的三维 MOF 结构中从未报道过。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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One ligand, two roles: novel pillar-layered metal–organic frameworks built with a 3D ligand and asymmetric inorganic nodes†

Herein, we show two cases of pillar-layered MOFs which are built solely with one kind of three-dimensional (3D) ditopic ligand. The ligand in both structures functions not only as an intralayer linker in the layer but also as a “pillar” between adjacent layers. Such multi-functionality of the linker is accompanied by uncommon asymmetric 10-c metal hexamer or 7-c tetramer nodes, which have never been reported in previous 3D MOF structures.

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来源期刊

Dalton Transactions 化学-无机化学与核化学

CiteScore

6.60

自引率

7.50%

发文量

1832

审稿时长

1.5 months

期刊介绍： Dalton Transactions is a journal for all areas of inorganic chemistry, which encompasses the organometallic, bioinorganic and materials chemistry of the elements, with applications including synthesis, catalysis, energy conversion/storage, electrical devices and medicine. Dalton Transactions welcomes high-quality, original submissions in all of these areas and more, where the advancement of knowledge in inorganic chemistry is significant.