将二氧化碳转化为分子多孔框架

IF 16.4 1区化学 Q1 CHEMISTRY, MULTIDISCIPLINARY Accounts of Chemical Research Pub Date : 2024-10-14 DOI:10.1021/acs.accounts.4c00519

Kentaro Kadota, Satoshi Horike

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引用次数: 0

摘要

将二氧化碳（CO2）转化为高附加值功能材料是实现碳中和社会的一大挑战。虽然二氧化碳是一种极具吸引力的可再生碳资源，其天然丰度很高，但由于其化学惰性，很难将二氧化碳转化为具有所需结构和功能的材料。基于分子的多孔材料，如金属有机框架（MOFs）和共价有机框架（COFs），是由基于分子的构建单元构成的可设计多孔固体。虽然 MOF/COFs 作为功能性多孔材料受到广泛关注，但由于缺乏将二氧化碳转化为分子基构建单元的合成指南，将二氧化碳转化为 MOF/COFs 的合成方法尚未得到探索。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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Conversion of Carbon Dioxide into Molecular-based Porous Frameworks

The conversion of carbon dioxide (CO₂) to value-added functional materials is a major challenge in realizing a carbon-neutral society. Although CO₂ is an attractive renewable carbon resource with high natural abundance, its chemical inertness has made the conversion of CO₂ into materials with the desired structures and functionality difficult. Molecular-based porous materials, such as metal–organic frameworks (MOFs) and covalent–organic frameworks (COFs), are designable porous solids constructed from molecular-based building units. While MOF/COFs attract wide attention as functional porous materials, the synthetic methods to convert CO₂ into MOF/COFs have been unexplored due to the lack of synthetic guidelines for converting CO₂ into molecular-based building units.

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来源期刊

Accounts of Chemical Research 化学-化学综合

CiteScore

31.40

自引率

1.10%

发文量

312

审稿时长

2 months

期刊介绍： Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance. Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.