用于可穿戴传感和水净化的氧化银集成离子聚合物复合材料

IF 5.5 Q1 ENGINEERING, CHEMICAL Chemical Engineering Journal Advances Pub Date : 2024-10-11 DOI:10.1016/j.ceja.2024.100651
Priya Khanduri , Varij Panwar , Pradeep Kumar Sharma , Gopinathan Anoop , Sanjeev Kumar , Sukho Park
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引用次数: 0

摘要

将金属纳米粒子(NPs)与离子聚合物混合物/复合材料结合在一起,在可穿戴传感器、软机械臂、生物医学设备的柔性人机界面以及水净化应用方面具有巨大的潜力,因此引起了人们的极大兴趣。然而,传统的 NPs 附着离子聚合物复合材料表现出一些局限性,如灵敏度(ΔR/R)低、降低总溶解固体(TDS)和磷酸盐(PO4-P)去除率低。在此,我们设计并开发了附着聚偏二氟乙烯(PVDF)/聚乙烯吡咯烷酮(PVP)/离子液体(IL)的花形氧化银(Ag2O)离子聚合物复合材料(IPCs),用于可穿戴传感和水净化。这些 IPC 分别在手腕运动 50°、手指运动 180°和下巴运动时显示出 50、10 和 3.5 的高 ΔR/R 值。根据记录,基于 Ag2O 的 IPC 显著降低了污水中的 TDS,从 3405 ppm 降至 1035 ppm,污水中的溶解氧(DO)水平从 1.2 mg/l 升至 6.8 mg/l,并去除污水中约 87.38% 的磷酸盐。由于 Ag2O 在 IPC 的孔隙中分布均匀,它在可穿戴设备和污水处理应用方面的性能得到了提高。
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Silver oxide integrated ionic polymer composite for wearable sensing and water purification
Integrating metal nanoparticles (NPs) with ionic polymer blends/composites showed immense interest for their potential in wearable sensors, soft robotic arms, flexible man-machine interfaces of biomedical devices, and water purification applications. However, conventional NPs attached ionic polymer composites exhibit limitations such as low sensitivity (ΔR/R), low total dissolved solids (TDS) reduction, and low phosphate (PO4-P) removal rate. Herein, ionic polymer composites (IPCs) using flower-shaped silver oxide (Ag2O) attached Poly (vinylidene fluoride) (PVDF)/ polyvinylpyrrolidone (PVP)/ionic liquid (IL) were designed and developed for wearable sensing and water purification. The IPCs demonstrated remarkably high ΔR/R values of 50, 10, and 3.5 corresponding to the wrist movement of 50°, finger movement of 180°, and chin movements respectively. The Ag2O-based IPC recorded a significant reduction of TDS from sewage water from 3405 ppm to 1035 ppm, elevated the dissolved oxygen (DO) levels in the sewage water from 1.2 mg/l to 6.8 mg/l, and removed approximately 87.38 % phosphate from sewage water. Due to the uniform distribution of Ag2O within pores of IPC, it demonstrated enhanced performance for wearable and wastewater treatment applications.
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来源期刊
Chemical Engineering Journal Advances
Chemical Engineering Journal Advances Engineering-Industrial and Manufacturing Engineering
CiteScore
8.30
自引率
0.00%
发文量
213
审稿时长
26 days
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