氯钌酰环戊三烯的合成与结构

IF 6.4 1区化学 Q1 CHEMISTRY, INORGANIC & NUCLEAR Inorganic Chemistry Frontiers Pub Date : 2024-10-22 DOI:10.1039/D4QI01833H

Zhenwei Chu, Zhishun Peng, Xu Cheng, Yuhui Hua, Guomei He, Jiangxi Chen and Guochen Jia

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摘要

通过 RuCl2(PPh3)3 与邻苯基二炔衍生物在过量盐酸存在下的反应，首次实现了氯钌环五三烯。光谱数据和 X 射线衍射对这些独特的氯钌环的结构进行了全面表征。此外，计算研究还证明了它们的芳香特性，使它们成为稀有芳香钌环家族的重要补充。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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Synthesis and structure of chlororuthenacyclopentatriene†

The first chlororuthenacyclopentatrienes have been realized by the reactions of RuCl₂(PPh₃)₃ with o-phenyldiyne derivatives in the presence of excess HCl. The structures of the unique chlororuthenacycles were fully characterized using spectroscopic data and X-ray diffraction. In addition, computational studies provided evidence for their aromatic character, making them an important supplement to the rare aromatic ruthenacycle family.

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