{"title":"氯钌酰环戊三烯的合成与结构","authors":"Zhenwei Chu, Zhishun Peng, Xu Cheng, Yuhui Hua, Guomei He, Jiangxi CHEN, Guochen Jia","doi":"10.1039/d4qi01833h","DOIUrl":null,"url":null,"abstract":"The first chlororuthenacyclopentatrienes have been realized by the reactions of RuCl2(PPh3)3 with o-phenyldiyne derivatives in the presence of excess HCl. The structures of the unique chlororuthenacycles were fully characterized by spectroscopic data and X-ray diffraction. In addition, computational studies provided the evidence for their aromatic character, making them as an important supplement to the rare aromatic ruthenacycle family.","PeriodicalId":79,"journal":{"name":"Inorganic Chemistry Frontiers","volume":null,"pages":null},"PeriodicalIF":6.1000,"publicationDate":"2024-10-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Synthesis and Structure of Chlororuthenacyclopentatriene\",\"authors\":\"Zhenwei Chu, Zhishun Peng, Xu Cheng, Yuhui Hua, Guomei He, Jiangxi CHEN, Guochen Jia\",\"doi\":\"10.1039/d4qi01833h\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The first chlororuthenacyclopentatrienes have been realized by the reactions of RuCl2(PPh3)3 with o-phenyldiyne derivatives in the presence of excess HCl. The structures of the unique chlororuthenacycles were fully characterized by spectroscopic data and X-ray diffraction. In addition, computational studies provided the evidence for their aromatic character, making them as an important supplement to the rare aromatic ruthenacycle family.\",\"PeriodicalId\":79,\"journal\":{\"name\":\"Inorganic Chemistry Frontiers\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":6.1000,\"publicationDate\":\"2024-10-22\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Inorganic Chemistry Frontiers\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://doi.org/10.1039/d4qi01833h\",\"RegionNum\":1,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, INORGANIC & NUCLEAR\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Inorganic Chemistry Frontiers","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1039/d4qi01833h","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
引用次数: 0
摘要
通过 RuCl2(PPh3)3 与邻苯基二炔衍生物在过量盐酸存在下的反应,首次实现了氯钌环五三烯。光谱数据和 X 射线衍射对这些独特的氯钌环的结构进行了全面表征。此外,计算研究还证明了它们的芳香特性,使它们成为稀有芳香钌环家族的重要补充。
Synthesis and Structure of Chlororuthenacyclopentatriene
The first chlororuthenacyclopentatrienes have been realized by the reactions of RuCl2(PPh3)3 with o-phenyldiyne derivatives in the presence of excess HCl. The structures of the unique chlororuthenacycles were fully characterized by spectroscopic data and X-ray diffraction. In addition, computational studies provided the evidence for their aromatic character, making them as an important supplement to the rare aromatic ruthenacycle family.