碳毡上包覆的 NiO/MnO2 作为超级电容器应用的电极材料。

IF 2.9 4区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Nanotechnology Pub Date : 2024-11-04 DOI:10.1088/1361-6528/ad87fa
Sadegh Azizi, Mohammad Bagher Askari, Seyed Mohammad Rozati, Mojtaba Masoumnezhad
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引用次数: 0

摘要

过渡金属氧化物用于超级电容器电极时,已显示出卓越的电荷存储能力。本研究在碳毡(CF)基底上水热合成了双金属镍和锰氧化物(NiO/MnO2)。在氢氧化钾电解液中的三电极系统中,对 NiO/MnO2/CF 电极进行了表征和检验。循环伏安法、电化学阻抗光谱法和电流静态充放电分析表明,电极在充电存储期间具有法拉第行为,比容量为 1627 F/g,在连续充放电循环 5000 次后,稳定性达到 96.8%。随后在双电极系统中进行了研究,以利用 NiO/MnO2/CF 电极构建对称的超级电容器。能量密度和功率密度分别为 43 瓦时/千克和 559 瓦时/千克。此外,还对所构建的超级电容器装置进行了连续 5000 次循环的稳定性测试,验证了其在充放电循环中 92% 的稳定性。最后,利用所制造的超级电容器为 LED 灯供电,成功地维持了 53 秒的照明。
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NiO/MnO2coated on carbon felt as an electrode material for supercapacitor applications.

Transition metal oxides have demonstrated excellent capability for charge storage when used in supercapacitor electrodes. This study undertook the hydrothermal synthesis of bimetallic nickel and manganese oxide (NiO/MnO2) on a carbon-felt (CF) substrate. NiO/MnO2/CF electrode was characterized and examined in a three-electrode system in a potassium hydroxide electrolyte. Cyclic voltammetry, electrochemical impedance spectroscopy, and galvanostatic charge-discharge analyses revealed Faradaic behavior during charge storage, a specific capacity of 1627 F g-1, and a stability of 96.8% after 5000 consecutive charge-discharge cycles. Subsequent investigations were conducted in a two-electrode system for constructing a symmetrical supercapacitor using the NiO/MnO2/CF electrode. The energy and power densities were determined as 43Wh kg-1and 559 W kg-1. Additionally, the stability of the constructed supercapacitor device was examined over 5000 consecutive cycles, verifying a 92% stability through charge-discharge cycles. Finally, the fabricated supercapacitor was utilized to power an LED lamp, successfully maintaining the illumination for 53 s.

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来源期刊
Nanotechnology
Nanotechnology 工程技术-材料科学:综合
CiteScore
7.10
自引率
5.70%
发文量
820
审稿时长
2.5 months
期刊介绍: The journal aims to publish papers at the forefront of nanoscale science and technology and especially those of an interdisciplinary nature. Here, nanotechnology is taken to include the ability to individually address, control, and modify structures, materials and devices with nanometre precision, and the synthesis of such structures into systems of micro- and macroscopic dimensions such as MEMS based devices. It encompasses the understanding of the fundamental physics, chemistry, biology and technology of nanometre-scale objects and how such objects can be used in the areas of computation, sensors, nanostructured materials and nano-biotechnology.
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