用于获得含磷和锆混合材料的绿色方法--溶胶-凝胶工艺。

IF 5 3区 化学 Q1 POLYMER SCIENCE Gels Pub Date : 2024-10-13 DOI:10.3390/gels10100656
Petru Merghes, Gheorghe Ilia, Bianca Maranescu, Narcis Varan, Vasile Simulescu
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引用次数: 0

摘要

溶胶-凝胶工艺是过去几十年来用于合成新型有机-无机含磷杂化材料的一种绿色方法。溶胶-凝胶合成法是一种绿色方法,因为它是在温和的条件下进行的,主要是在室温下用水或酒精作为溶剂。因此,溶胶-凝胶法是获得金属膦酸盐网络的一种很有前景的方法。除了磷之外,所获得的混合材料还可能含有钛、锆、硼和其他元素,这些元素都会影响其特性。溶胶-凝胶过程分为两个步骤:第一步是溶胶形成,第二步是向凝胶相过渡。换句话说,溶胶-凝胶过程将前驱体转化为胶体溶液(溶胶),然后形成网络(凝胶)。利用溶胶-凝胶法,可以将不同的有机分子引入无机基体,从而形成有机-无机混合结构(有时也称为有机-无机共聚物)。
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The Sol-Gel Process, a Green Method Used to Obtain Hybrid Materials Containing Phosphorus and Zirconium.

The sol-gel process is a green method used in the last few decades to synthesize new organic-inorganic phosphorus-containing hybrid materials. The sol-gel synthesis is a green method because it takes place in mild conditions, mostly by using water or alcohol as solvents, at room temperature. Therefore, the sol-gel method is, among others, a promising route for obtaining metal-phosphonate networks. In addition to phosphorus, the obtained hybrid materials could also contain titanium, zirconium, boron, and other elements, which influence their properties. The sol-gel process has two steps: first, the sol formation, and second, the transition to the gel phase. In other words, the sol-gel process converts the precursors into a colloidal solution (sol), followed by obtaining a network (gel). By using the sol-gel method, different organic moieties could be introduced into an inorganic matrix, resulting in organic-inorganic hybrid structures (sometimes they are also referred as organic-inorganic copolymers).

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来源期刊
Gels
Gels POLYMER SCIENCE-
CiteScore
4.70
自引率
19.60%
发文量
707
审稿时长
11 weeks
期刊介绍: The journal Gels (ISSN 2310-2861) is an international, open access journal on physical (supramolecular) and chemical gel-based materials. Our aim is to encourage scientists to publish their experimental and theoretical results in as much detail as possible. Therefore, there is no restriction on the maximum length of the papers, and full experimental details must be provided so that the results can be reproduced. Short communications, full research papers and review papers are accepted formats for the preparation of the manuscripts. Gels aims to serve as a reference journal with a focus on gel materials for researchers working in both academia and industry. Therefore, papers demonstrating practical applications of these materials are particularly welcome. Occasionally, invited contributions (i.e., original research and review articles) on emerging issues and high-tech applications of gels are published as special issues.
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