用于获得含磷和锆混合材料的绿色方法--溶胶-凝胶工艺。

IF 5 3区 化学 Q1 POLYMER SCIENCE Gels Pub Date : 2024-10-13 DOI:10.3390/gels10100656
Petru Merghes, Gheorghe Ilia, Bianca Maranescu, Narcis Varan, Vasile Simulescu
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引用次数: 0

摘要

溶胶-凝胶工艺是过去几十年来用于合成新型有机-无机含磷杂化材料的一种绿色方法。溶胶-凝胶合成法是一种绿色方法,因为它是在温和的条件下进行的,主要是在室温下用水或酒精作为溶剂。因此,溶胶-凝胶法是获得金属膦酸盐网络的一种很有前景的方法。除了磷之外,所获得的混合材料还可能含有钛、锆、硼和其他元素,这些元素都会影响其特性。溶胶-凝胶过程分为两个步骤:第一步是溶胶形成,第二步是向凝胶相过渡。换句话说,溶胶-凝胶过程将前驱体转化为胶体溶液(溶胶),然后形成网络(凝胶)。利用溶胶-凝胶法,可以将不同的有机分子引入无机基体,从而形成有机-无机混合结构(有时也称为有机-无机共聚物)。
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The Sol-Gel Process, a Green Method Used to Obtain Hybrid Materials Containing Phosphorus and Zirconium.

The sol-gel process is a green method used in the last few decades to synthesize new organic-inorganic phosphorus-containing hybrid materials. The sol-gel synthesis is a green method because it takes place in mild conditions, mostly by using water or alcohol as solvents, at room temperature. Therefore, the sol-gel method is, among others, a promising route for obtaining metal-phosphonate networks. In addition to phosphorus, the obtained hybrid materials could also contain titanium, zirconium, boron, and other elements, which influence their properties. The sol-gel process has two steps: first, the sol formation, and second, the transition to the gel phase. In other words, the sol-gel process converts the precursors into a colloidal solution (sol), followed by obtaining a network (gel). By using the sol-gel method, different organic moieties could be introduced into an inorganic matrix, resulting in organic-inorganic hybrid structures (sometimes they are also referred as organic-inorganic copolymers).

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来源期刊
Gels
Gels POLYMER SCIENCE-
CiteScore
4.70
自引率
19.60%
发文量
707
审稿时长
11 weeks
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