在全固态锌-石墨电池中应用 Simonkolleite 方面的突破

Energy Storage Pub Date : 2024-10-23 DOI:10.1002/est2.70071
Yi-Fen Hsiao, Fei-Yi Hung, Jun-Ren Zhao
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引用次数: 0

摘要

为了提高锌固态电池的电化学性能,我们引入了西蒙柯莱石作为新型阳极材料。黝帘石表面存在氧空位,具有电学和化学活性;这些空位可作为 n 型供体,显著提高材料的导电性。在这项研究中,我们采用一种简单、经济的方法合成了黝帘石,并将其用作阳极。全固态锌电池结合了矽孔沸石阳极、硅酸钠(SS)电解质和石墨薄膜(GF)阴极。我们的电池配置(锡芒硝/英戈特 SS/GF)达到了 1280 mAh g-1 的高容量,并显示出更高的循环稳定性。这种大型模块电池还能为电机风扇装置供电 1 小时 19 分钟。
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A Breakthrough in the Application of Simonkolleite in All-Solid-State Zn-Graphite Battery

To enhance the electrochemical performance of the Zn solid-state battery, we introduce simonkolleite as a novel anode material. With oxygen vacancies on its surface, simonkolleite exhibits both electrical and chemical activity; these vacancies serve as n-type donors, significantly improving the material's conductivity. In this research, simonkolleite is synthesized using a straightforward and cost-effective method and employed as the anode. The all-solid-state Zn battery combines the simonkolleite anode, sodium silicate (SS) electrolyte, and graphite film (GF) cathode. Our battery configuration (simonkolleite/Ingot SS/GF) achieves a high 1280 mAh g−1 capacity and demonstrates improved cyclic stability. The large-scale module battery can also power a motor-fan unit for 1 h and 19 min.

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