用于甘油选择性缩醛化的新型微孔有机-无机混合磷酸钛

IF 4.2 2区化学 Q2 CHEMISTRY, MULTIDISCIPLINARY Chemical Communications Pub Date : 2024-12-02 Epub Date: 2024-11-04 DOI:10.1039/d4cc04799k

Bhabani Malakar , Sudip Bhattacharjee , Nhat Quang Minh Tran , Tan Le Hoang Doan , Thang Bach Phan , Sayantan Chongdar , Asim Bhaumik

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引用次数: 0

摘要

通过在磷酸钛框架中加入 5- 氨基水杨酸（5-ASA），我们开发出一种合成高酸性微孔杂化磷酸钛材料（H-TiPOx）的新策略。这种新型 H-TiPOx 可用作布氏酸催化剂，其总表面酸度高达 5.9 mmol g-1，可高效催化丰富的生物质衍生甘油缩醛为索酮醛，选择性超过 99%。

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A new microporous organic–inorganic hybrid titanium phosphate for selective acetalization of glycerol†

We developed a novel strategy for synthesizing a highly acidic microporous hybrid titanium phosphate material () by incorporating 5-aminosalicylic acid (5-ASA) into the titanium phosphate framework. This new serves as a Brønsted acid catalyst, exhibiting remarkable total surface acidity of 5.9 mmol g⁻¹ and it efficiently catalyzes the acetalization of abundant biomass derived glycerol to solketal with over 99% selectivity.

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来源期刊

Chemical Communications 化学-化学综合

CiteScore

8.60

自引率

4.10%

发文量

2705

审稿时长

1.4 months

期刊介绍： ChemComm (Chemical Communications) is renowned as the fastest publisher of articles providing information on new avenues of research, drawn from all the world''s major areas of chemical research.