清洁能源技术:使用 Co/SBA-15 催化剂在连续反应器中加氢处理废轮胎热解油 (WTPO) 使其成为柴油燃料

P. Tamizhdurai , P. Arthi , V.L. Mangesh , P. Santhana Krishnan , Nadavala Siva Kumar , P. Saravanan , A. Subramani , P. Sasikumar , Mohammed F. Alotibi , Salwa B. Alreshaidan , Abdulaziz A.M. Abahussain , Ahmed S. Al-Fatesh , R. Kumaran
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引用次数: 0

摘要

对可持续燃料来源和高效废物管理的需求促使研究人员探索将废物转化为燃料的创新方法。其中一个很有前景的方法是利用 100% 的轮胎油 (TO),这可以为处理废轮胎提供一个有利可图且环保的解决方案。随着化石燃料成本上升、环境问题和废轮胎填埋的挑战,人们对作为替代能源的废轮胎热解油(WTPO)越来越感兴趣。本研究使用金属催化剂(特别是 Co/SBA-15)对加氢处理的废轮胎热解油(HWTPO)进行了分析。该方法包括使用金属催化剂水解 WTPO,评估其物理化学特性、与石油产品相比的配方效率以及柴油发动机性能,如对燃料消耗、燃烧和排放的影响。结果发现,合成 HWTPO 的化学和物理特性与欧洲柴油规格(欧洲标准 590)相当。在加氢处理条件(80 巴和 375 °C)下,Co/SBA-15 催化剂产生的异构烷烃、正构烷烃和芳烃的数量几乎等同于 100% 柴油。HWTPO 证明了最大限度减少温室气体排放和提高柴油发动机性能的潜力。HWTPO 的有利特性表明,废轮胎热解油可以成为一种可行的运输燃料。
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Clean energy technology: Hydro-processing of waste tyre pyrolysis oil (WTPO) to diesel fuel in a continuous reactor using Co/SBA-15 catalyst
The need for sustainable fuel sources and efficient waste management has led researchers to explore innovative methods for converting waste into fuel. One promising avenue is the utilization of 100 % tyre oil (TO), which could offer a profitable and environmentally friendly solution for disposing of waste tyres. With rising fossil fuel costs, environmental concerns, and the challenges of waste tyre landfilling, there is increased interest in waste tyre pyrolysis oils (WTPO) as an alternative energy source. This study examines the hydro processed WTPO (HWTPO) was analysed using a metallic catalyst, specifically Co/SBA-15. This method involves hydrolysing WTPO with the metallic catalyst, assessing the physical-chemical properties, formulation efficiency compared to petroleum products, and diesel engine performance like the impact on fuel consumption, combustion, and emissions. The synthetic HWTPO's chemical and physical properties were found to be comparable to European diesel specifications (European standard 590). Under hydroprocessing conditions (80 bar and 375 °C), the Co/SBA-15 catalyst produced isoalkanes, n-alkanes, and aromatics in quantities nearly equivalent to 100 % diesel. HWTPO demonstrated the potential to maximize greenhouse gas emissions reduction and enhance the performance of diesel-powered engines. The favourable properties of HWTPO suggest that waste tyre pyrolysis oil could be a viable transportation fuel.
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