Yi Gao , Ziyan Zhang , Jinjuan Cheng , Chaoqiang Liu , Kechao Zhou , Xueping Gan
{"title":"不同老化条件下 Cu-15Ni-8Sn 合金的低温氧化行为","authors":"Yi Gao , Ziyan Zhang , Jinjuan Cheng , Chaoqiang Liu , Kechao Zhou , Xueping Gan","doi":"10.1016/j.matchar.2024.114519","DOIUrl":null,"url":null,"abstract":"<div><div>Cu-15Ni-8Sn (wt%) alloy has been widely used in engineering applications due to its excellent mechanical strength, wear, and corrosion resistance. However, low-temperature oxidation (LTO) poses a significant challenge, restricting its further application and longevity. In this study, the low-temperature oxidation behavior of the Cu-15Ni-8Sn alloy under different aging condition was investigated using multi-scale characterization by SEM and TEM. The characterization results reveal the oxide films of the aged sample contain tri-layers at low temperature, the outermost layer is dominated by CuO and Cu<sub>2</sub>O, the middle oxide layer contains of Cu<sub>2</sub>O, NiO, SnO<sub>2</sub> and SnO, and the inner oxide layer is composed of NiO and SnO<sub>2</sub>. In addition, the as-quenched sample has superior oxidation resistance compared to the aged samples, and the oxidation resistance of the aged samples decreases with the increase of aging time. That is, there is a trade-off between hardness and oxidation resistance in aged Cu-15Ni-8Sn alloys. Therefore, these findings provided a way to adjust the aging parameter based on specific service conditions.</div></div>","PeriodicalId":18727,"journal":{"name":"Materials Characterization","volume":"218 ","pages":"Article 114519"},"PeriodicalIF":4.8000,"publicationDate":"2024-11-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Low-temperature oxidation behaviors of Cu-15Ni-8Sn alloy in different aging conditions\",\"authors\":\"Yi Gao , Ziyan Zhang , Jinjuan Cheng , Chaoqiang Liu , Kechao Zhou , Xueping Gan\",\"doi\":\"10.1016/j.matchar.2024.114519\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>Cu-15Ni-8Sn (wt%) alloy has been widely used in engineering applications due to its excellent mechanical strength, wear, and corrosion resistance. However, low-temperature oxidation (LTO) poses a significant challenge, restricting its further application and longevity. In this study, the low-temperature oxidation behavior of the Cu-15Ni-8Sn alloy under different aging condition was investigated using multi-scale characterization by SEM and TEM. The characterization results reveal the oxide films of the aged sample contain tri-layers at low temperature, the outermost layer is dominated by CuO and Cu<sub>2</sub>O, the middle oxide layer contains of Cu<sub>2</sub>O, NiO, SnO<sub>2</sub> and SnO, and the inner oxide layer is composed of NiO and SnO<sub>2</sub>. In addition, the as-quenched sample has superior oxidation resistance compared to the aged samples, and the oxidation resistance of the aged samples decreases with the increase of aging time. That is, there is a trade-off between hardness and oxidation resistance in aged Cu-15Ni-8Sn alloys. Therefore, these findings provided a way to adjust the aging parameter based on specific service conditions.</div></div>\",\"PeriodicalId\":18727,\"journal\":{\"name\":\"Materials Characterization\",\"volume\":\"218 \",\"pages\":\"Article 114519\"},\"PeriodicalIF\":4.8000,\"publicationDate\":\"2024-11-02\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Materials Characterization\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S1044580324009008\",\"RegionNum\":2,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"MATERIALS SCIENCE, CHARACTERIZATION & TESTING\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Materials Characterization","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S1044580324009008","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"MATERIALS SCIENCE, CHARACTERIZATION & TESTING","Score":null,"Total":0}
Low-temperature oxidation behaviors of Cu-15Ni-8Sn alloy in different aging conditions
Cu-15Ni-8Sn (wt%) alloy has been widely used in engineering applications due to its excellent mechanical strength, wear, and corrosion resistance. However, low-temperature oxidation (LTO) poses a significant challenge, restricting its further application and longevity. In this study, the low-temperature oxidation behavior of the Cu-15Ni-8Sn alloy under different aging condition was investigated using multi-scale characterization by SEM and TEM. The characterization results reveal the oxide films of the aged sample contain tri-layers at low temperature, the outermost layer is dominated by CuO and Cu2O, the middle oxide layer contains of Cu2O, NiO, SnO2 and SnO, and the inner oxide layer is composed of NiO and SnO2. In addition, the as-quenched sample has superior oxidation resistance compared to the aged samples, and the oxidation resistance of the aged samples decreases with the increase of aging time. That is, there is a trade-off between hardness and oxidation resistance in aged Cu-15Ni-8Sn alloys. Therefore, these findings provided a way to adjust the aging parameter based on specific service conditions.
期刊介绍：
Materials Characterization features original articles and state-of-the-art reviews on theoretical and practical aspects of the structure and behaviour of materials.
The Journal focuses on all characterization techniques, including all forms of microscopy (light, electron, acoustic, etc.,) and analysis (especially microanalysis and surface analytical techniques). Developments in both this wide range of techniques and their application to the quantification of the microstructure of materials are essential facets of the Journal.
The Journal provides the Materials Scientist/Engineer with up-to-date information on many types of materials with an underlying theme of explaining the behavior of materials using novel approaches. Materials covered by the journal include:
Metals & Alloys
Ceramics
Nanomaterials
Biomedical materials
Optical materials
Composites
Natural Materials.
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