环境净化的革命:MOFs 作为污染修复催化剂的演变

IF 3.9 3区 化学 Q2 CHEMISTRY, MULTIDISCIPLINARY RSC Advances Pub Date : 2024-11-20 DOI:10.1039/D4RA05642F
Umme Farwa, Zeshan Ali Sandhu, Azwa Kiran, Muhammad Asam Raza, Sufyan Ashraf, Hamza Gulzarab, Muhammad Fiaz, Adnan Malik and Abdullah G. Al-Sehemi
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引用次数: 0

摘要

全球生态安全和公众健康问题要求开发新的可持续污染修复理念。近年来,金属有机框架(MOF)是一种新兴技术,具有显著的潜力,已被用于环境修复。MOF 是由金属或多阴离子与配体配位形成的网络,含有可定制的有机成分。MOFs 的有趣之处在于表面积大、孔隙率可调、功能多样,以及对污染物的吸附、催化和降解具有很高的可预测性。它是一种固体材料,在与环境污染物的斗争中占有独特的地位。MOFs 的主要优点之一是对重金属、有机物、温室气体、水和土壤等多种污染物具有选择性吸附。只有孔径大小和化学成分结合得当的颗粒才能实现这种选择性,这种选择性源于其高度的特异性。此外,它们还具有很强的催化能力,可通过光催化、芬顿类反应和氧化降解等不同方法去除污染物。通过在 MOFs 框架内生成可移动的活性位点,我们不仅能确保对污染物的高亲和性,还能有效地将有毒化学物质转化为危害较小甚至惰性的最终产物。然而,随着环保型部件被可重复使用的部件所取代,以及基于 MOFs 制造出可通过多种方式清除污染物的系统,MOFs 的长期稳定性变得越来越重要。与其他去除工艺相比,MOF 可以减少废物产生和能源消耗。MOF 技术以其无穷无尽的能力为环境清洁问题带来了解决方案,在各个领域都能灵活地解决问题。对 MOF 合成和原理的研究将使研究人员充分了解 MOF 在解决环境问题方面的潜力,从而使我们的世界变得更加美好。
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Revolutionizing environmental cleanup: the evolution of MOFs as catalysts for pollution remediation

The global problem of ecological safety and public health necessitates, the development of new sustainable ideas for pollution remediation. In recent development, metal–organic frameworks (MOF) are the emerging technology with remarkable potential, which have been employed in environmental remediation. MOFs are networks that are created by the coordination of metals or polyanions with ligands and contain organic components that can be customized. The interesting features of MOFs are a large surface area, tuneable porosity, functional diversity, and high predictability of pollutant adsorption, catalysis, and degradation. It is a solid material that occupies a unique position in the war against environmental pollutants. One of the main benefits of MOFs is that they exhibit selective adsorption of a wide range of pollutants, including heavy metals, organics, greenhouse gases, water and soil. Only particles with the right combination of pore size and chemical composition will achieve this selectivity, derived from the high level of specificity. Besides, they possess high catalytic ability for the removal of pollutants by means of different methods such as photocatalysis, Fenton-like reactions, and oxidative degradation. By generating mobile active sites within the framework of MOFs, we can not only ensure high affinity for pollutants but also effective transformation of toxic chemicals into less harmful or even inert end products. However, the long-term stability of MOFs is becoming more important as eco-friendly parts are replaced with those that can be used repeatedly, and systems based on MOFs that can remove pollutants in more than one way are fabricated. MOFs can reduce waste production, energy consumption as compared to the other removal process. With its endless capacities, MOF technology brings a solution to the environmental cleansing problem, working as a flexible problem solver from one field to another. The investigation of MOF synthesis and principles will allow researchers to fully understand the potential of MOFs in environmental problem solving, making the world a better place for all of us.

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来源期刊
RSC Advances
RSC Advances chemical sciences-
CiteScore
7.50
自引率
2.60%
发文量
3116
审稿时长
1.6 months
期刊介绍: An international, peer-reviewed journal covering all of the chemical sciences, including multidisciplinary and emerging areas. RSC Advances is a gold open access journal allowing researchers free access to research articles, and offering an affordable open access publishing option for authors around the world.
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