Yangyang Wang , Xiegeng Wang , Long Li , Liwen Zhang
{"title":"降低结晶速度以制备高效柔性锡基过氧化物太阳能电池","authors":"Yangyang Wang , Xiegeng Wang , Long Li , Liwen Zhang","doi":"10.1016/j.mlblux.2024.100235","DOIUrl":null,"url":null,"abstract":"<div><div>In this study, five hydrochlorides are used as additives to slow the crystallization rate between SnI<sub>2</sub> and AI (A<sup>+</sup>=MA<sup>+</sup>, FA<sup>+</sup>, Cs<sup>+</sup>) to prepare high-quality perovskite films. This study on film morphology, crystallization and non-radiative recombination demonstrates the effects of organic amine cations with different chain lengths on the quality of thin films. A flexible solar cell device with a lead-free perovskite film doped with PACl is also obtained achieving an efficiency of 5.52 %.</div></div>","PeriodicalId":18245,"journal":{"name":"Materials Letters: X","volume":"24 ","pages":"Article 100235"},"PeriodicalIF":2.2000,"publicationDate":"2024-11-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Slowing the crystallization speed to prepare high-efficiency flexible tin-based perovskite solar cells\",\"authors\":\"Yangyang Wang , Xiegeng Wang , Long Li , Liwen Zhang\",\"doi\":\"10.1016/j.mlblux.2024.100235\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>In this study, five hydrochlorides are used as additives to slow the crystallization rate between SnI<sub>2</sub> and AI (A<sup>+</sup>=MA<sup>+</sup>, FA<sup>+</sup>, Cs<sup>+</sup>) to prepare high-quality perovskite films. This study on film morphology, crystallization and non-radiative recombination demonstrates the effects of organic amine cations with different chain lengths on the quality of thin films. A flexible solar cell device with a lead-free perovskite film doped with PACl is also obtained achieving an efficiency of 5.52 %.</div></div>\",\"PeriodicalId\":18245,\"journal\":{\"name\":\"Materials Letters: X\",\"volume\":\"24 \",\"pages\":\"Article 100235\"},\"PeriodicalIF\":2.2000,\"publicationDate\":\"2024-11-20\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Materials Letters: X\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S2590150824000085\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"MATERIALS SCIENCE, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Materials Letters: X","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2590150824000085","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
Slowing the crystallization speed to prepare high-efficiency flexible tin-based perovskite solar cells
In this study, five hydrochlorides are used as additives to slow the crystallization rate between SnI2 and AI (A+=MA+, FA+, Cs+) to prepare high-quality perovskite films. This study on film morphology, crystallization and non-radiative recombination demonstrates the effects of organic amine cations with different chain lengths on the quality of thin films. A flexible solar cell device with a lead-free perovskite film doped with PACl is also obtained achieving an efficiency of 5.52 %.